Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by pd (oac)(2)/so under solvent-free conditions
文献类型：期刊论文
| 作者 | Liu, Junhua1,2; Wang, Fang1,2; Sun, Kunpeng1; Xu, Xianlun1 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2008-03-01 |
| 卷号 | 9期号:3页码:386-390 |
| ISSN号 | 1566-7367 |
| 关键词 | Alcohols Aldehydes Hydrogen peroxide Oxidation Palladium Sodium oxalate |
| DOI | 10.1016/j.catcom.2007.07.026 |
| 通讯作者 | Xu, xianlun(xlxu@lzb.ac.cn) |
| 英文摘要 | With oxygen that was supplied by hydrogen peroxide as oxidant, secondary and primary aliphatic alcohols, primary allylic alcohols could be efficiently oxidized to aldehydes or ketones in high yields in the presence of pd (oac)(2)-sodium oxalate (so) under solvent-free conditions, it is a high yielding and operationally simple method. acetic acid is testified to attend the reaction, the acetate ligands are environed to serve two purposes: as a ligand for the pd-11 center and as a base to deprotonate the pd-bound alcohol, but acetic acid has not shown in previous bidentate ligands systems, so a mechanism is proposed on the basis of the mechanisms reported by the pioneers. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | AEROBIC OXIDATION ; WATER ; OXYGEN ; LIGAND |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000252293400012 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2389754 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Xianlun |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Junhua,Wang, Fang,Sun, Kunpeng,et al. Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by pd (oac)(2)/so under solvent-free conditions[J]. Catalysis communications,2008,9(3):386-390. |
| APA | Liu, Junhua,Wang, Fang,Sun, Kunpeng,&Xu, Xianlun.(2008).Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by pd (oac)(2)/so under solvent-free conditions.Catalysis communications,9(3),386-390. |
| MLA | Liu, Junhua,et al."Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by pd (oac)(2)/so under solvent-free conditions".Catalysis communications 9.3(2008):386-390. |
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来源：中国科学院大学
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