Investigations on the solid state interaction between LiAlH4 and NaNH2
文献类型：期刊论文
| 作者 | Chua, Yong Shen2; Wu, Guotao1; Xiong, Zhitao1; Chen, Ping1,2 |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 183期号:9页码:2040-2044 |
| 关键词 | Hydrogen storage Cation exchange NaAlH4 LiNH2 |
| 产权排序 | 1;2 |
| 通讯作者 | 熊智涛 |
| 英文摘要 | in this paper, two lialh4-nanh2 samples with lialh4 to nanh2 molar ratio of 1/2 and 2/1 were investigated, respectively. it was observed that both samples evolved 2 equiv h-2 in the ball milling process, however, the reaction pathways were different. for the lialh4-nanh2 (1/2) sample, li3na(nh2)(4) and naalh4 were formed through cation exchange between reactants. the naalh4 formed further reacts with li3na(nh2)(4) and nanh2 to give h-2, nah and lialn2h2. for the lialh4-nanh2 (2/1) sample, li3na(nh2)(4), linh2 and naalh4 were formed firstly through the same cation exchange process. the resulting linh2 reacts with the remaining lialh4 and produces h-2 and li2alnh2. (c) 2010 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | reversible hydrogen storage ; thermal-decomposition ; chemical-reaction ; ammonia borane ; al-27 nmr ; lithium ; system ; lih ; dehydrogenation ; hydrides |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000282139600020 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103457]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore |
| 推荐引用方式 GB/T 7714 | Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,et al. Investigations on the solid state interaction between LiAlH4 and NaNH2[J]. journal of solid state chemistry,2010,183(9):2040-2044. |
| APA | Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,&Chen, Ping.(2010).Investigations on the solid state interaction between LiAlH4 and NaNH2.journal of solid state chemistry,183(9),2040-2044. |
| MLA | Chua, Yong Shen,et al."Investigations on the solid state interaction between LiAlH4 and NaNH2".journal of solid state chemistry 183.9(2010):2040-2044. |
入库方式： OAI收割
来源：大连化学物理研究所
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