Aggregates of amphiphilic fluorinated copolymers and their encapsulating and unloading homopolymer behaviors
文献类型：期刊论文
| 作者 | Xu, Shouping1,2; Liu, Weiqu1 |
| 刊名 | Journal of polymer science part b-polymer physics
 |
| 出版日期 | 2008-06-01 |
| 卷号 | 46期号:11页码:1000-1006 |
| 关键词 | Amphiphiles Diblock copolymers Living polymerization |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.21432 |
| 通讯作者 | Liu, weiqu(liuwq@gic.ac.cn) |
| 英文摘要 | Amphiphilic fluorinated block copolymers synthesized via reversible addition-fragmentation chain transfer polymerization were used for the preparation of aggregates of various morphologies. first, dissolve the copolymer in 2-butanone; second, add a precipitant solvent, which was the mixture of water and methanol, to induce the aggregation of the hydrophobic fluorinated block. with a hydrophilic tail and a very hydrophobic segment, these copolymers are likely to self-assemble in solution and form aggregates. observed by tem, spheres, rods, and vesicles can be formed by changing the precipitant mixture contents. besides, these aggregates were found to be able to carry hydrophobic fluorinated homopolymers, and two suggested processes have been proposed to explain their morphology changes from original spheres, rods and vesicles into larger size spheres. finally, hollow bilayer spheres and tubules can be achieved after extracting homopolymers in the center of the newly formed spheres. (c) 2008 wiley periodicals, inc. |
| WOS关键词 | BLOCK IONOMER COMPLEXES ; RADICAL POLYMERIZATION ; AQUEOUS-SOLUTION ; DILUTE-SOLUTION ; PHASE-BEHAVIOR ; WATER ; ACID) ; MORPHOLOGY ; PARTICLES ; MIXTURES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000256390300002 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2389800 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Weiqu |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Shouping,Liu, Weiqu. Aggregates of amphiphilic fluorinated copolymers and their encapsulating and unloading homopolymer behaviors[J]. Journal of polymer science part b-polymer physics,2008,46(11):1000-1006. |
| APA | Xu, Shouping,&Liu, Weiqu.(2008).Aggregates of amphiphilic fluorinated copolymers and their encapsulating and unloading homopolymer behaviors.Journal of polymer science part b-polymer physics,46(11),1000-1006. |
| MLA | Xu, Shouping,et al."Aggregates of amphiphilic fluorinated copolymers and their encapsulating and unloading homopolymer behaviors".Journal of polymer science part b-polymer physics 46.11(2008):1000-1006. |
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来源：中国科学院大学
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