Differences between ZSM-5 and ZSM-11 zeolite catalysts in 1-hexene aromatization and isomerization
文献类型:期刊论文
作者 | Zhang, Ling1,2; Liu, Huijuan1,2; Li, Xiujie1; Xie, Sujuan1; Wang, Yuzhong1; Xin, Wenjie1; Liu, Shenglin1; Xu, Longya1 |
刊名 | fuel processing technology
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出版日期 | 2010-05-01 |
卷号 | 91期号:5页码:449-455 |
关键词 | ZSM-5 zeolite ZSM-11 zeolite 1-hexene Aromatization Isomerization |
产权排序 | 1;1 |
通讯作者 | 徐龙伢 |
英文摘要 | zsm-5 and zsm-11 zeolites with high crystallinity are synthesized and tested in the aromatization and isomerization reactions of 1-hexene at 370 degrees c in a continuous flow fixed bed. the results indicate that zsm-5 and zsm-11 zeolites possess similar acid site amount and strength, and most of the acid sites belong to bronsted acid. when the zsm-5 and zsm-11 zeolites were used as catalysts, the aromatics selectivity over zsm-11 catalyst was higher than that over zsm-5 catalyst in contrast to i-paraffins selectivity, maybe attributed to that the c(7) and c(8) aromatics have an easier exit from the zsm-11 zeolite. moreover, the decrease of particle size can present superior aromatics selectivity and less i-paraffins selectivity in the aromatization and isomerization of 1-hexene over the zsm-11 catalyst. (c) 2009 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; energy & fuels ; engineering, chemical |
研究领域[WOS] | chemistry ; energy & fuels ; engineering |
关键词[WOS] | shape-selectivity ; hzsm-5 ; propene ; ethene ; mel |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000277822200002 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/103485] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Ling,Liu, Huijuan,Li, Xiujie,et al. Differences between ZSM-5 and ZSM-11 zeolite catalysts in 1-hexene aromatization and isomerization[J]. fuel processing technology,2010,91(5):449-455. |
APA | Zhang, Ling.,Liu, Huijuan.,Li, Xiujie.,Xie, Sujuan.,Wang, Yuzhong.,...&Xu, Longya.(2010).Differences between ZSM-5 and ZSM-11 zeolite catalysts in 1-hexene aromatization and isomerization.fuel processing technology,91(5),449-455. |
MLA | Zhang, Ling,et al."Differences between ZSM-5 and ZSM-11 zeolite catalysts in 1-hexene aromatization and isomerization".fuel processing technology 91.5(2010):449-455. |
入库方式: OAI收割
来源:大连化学物理研究所
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