Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling
文献类型：期刊论文
| 作者 | Chen, Qing-An2; Dong, Xiang3; Chen, Mu-Wang2; Wang, Duo-Sheng2; Zhou, Yong-Gui1; Li, Yu-Xue1 |
| 刊名 | organic letters
 |
| 出版日期 | 2010-05-07 |
| 卷号 | 12期号:9页码:1928-1931 |
| 产权排序 | 1;1 |
| 通讯作者 | 周永贵 |
| 英文摘要 | a series of axially chiral bis-sulfoxide ligands have been efficiently synthesized via oxidative coupling with high diastereoselectivities. the axial chirality is well controlled by the tert-butylsulfinyl or the p-tolylsulfinyl group. these axially chiral bis-sulfoxides proved to be remarkably efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to 2-cyclohexenone with 99% ee. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalyzed asymmetric 1,4-addition ; arylboronic acids ; diene ligands ; enantiopure sulfoxides ; diphosphine ligands ; allylation ; organocatalysts ; aldehydes ; imines ; allyltrichlorosilane |
| 收录类别 | SCI ; IC ; CCR |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000277212800010 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103493]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Univ Sci & Technol China, Dept Phys Chem, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qing-An,Dong, Xiang,Chen, Mu-Wang,et al. Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling[J]. organic letters,2010,12(9):1928-1931. |
| APA | Chen, Qing-An,Dong, Xiang,Chen, Mu-Wang,Wang, Duo-Sheng,Zhou, Yong-Gui,&Li, Yu-Xue.(2010).Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling.organic letters,12(9),1928-1931. |
| MLA | Chen, Qing-An,et al."Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling".organic letters 12.9(2010):1928-1931. |
入库方式： OAI收割
来源：大连化学物理研究所
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