Porous silica nanocapsules and nanospheres: dynamic self-assembly synthesis and application in controlled release
文献类型:期刊论文
作者 | Chen, Hongmin1,2,4; He, Junhui1,2; Tang, Huamin3; Yan, Chunxiao3 |
刊名 | Chemistry of materials
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出版日期 | 2008-09-23 |
卷号 | 20期号:18页码:5894-5900 |
ISSN号 | 0897-4756 |
DOI | 10.1021/cm801411y |
通讯作者 | He, junhui(jhhe@mail.ipc.ac.cn) |
英文摘要 | In this work, porous silica nanocapsules and silica nanospheres have been successfully fabricated by a novel combination of stabilizing condensation and dynamic self-assembly. when ethyl ether was used as a cosolvent, porous silica nanocapsules were obtained. in contrast, when 2-ethoxyethanol was used, silica porous nanospheres were produced. the silica nanostructures were characterized by small-angle x-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, and nitrogen adsorption-desorption measurements. they had high brunauer-emmett-teller specific surface areas and large pore volumes. the order of their pore structures increased with an increase of the corresponding cosolvent. in situ encapsulation of organic molecules into silica nanocapsules and their controlled release were further investigated by using pyrene as a typical example. as many dyes, drugs, etc. are organic molecules, the current approaches will doubtlessly open many possibilities toward biological and technological applications. |
WOS关键词 | MESOPOROUS SILICA ; HOLLOW SPHERES ; TEMPLATED SYNTHESIS ; GUEST MOLECULES ; SHELL STRUCTURE ; SIZE ; SURFACTANT ; PARTICLES ; NANOPARTICLES ; MECHANISM |
WOS研究方向 | Chemistry ; Materials Science |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000259275000023 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2390030 |
专题 | 中国科学院大学 |
通讯作者 | He, Junhui |
作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Funct Nanomat Lab, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 3.Inst Chem Def, Beijing 102205, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Hongmin,He, Junhui,Tang, Huamin,et al. Porous silica nanocapsules and nanospheres: dynamic self-assembly synthesis and application in controlled release[J]. Chemistry of materials,2008,20(18):5894-5900. |
APA | Chen, Hongmin,He, Junhui,Tang, Huamin,&Yan, Chunxiao.(2008).Porous silica nanocapsules and nanospheres: dynamic self-assembly synthesis and application in controlled release.Chemistry of materials,20(18),5894-5900. |
MLA | Chen, Hongmin,et al."Porous silica nanocapsules and nanospheres: dynamic self-assembly synthesis and application in controlled release".Chemistry of materials 20.18(2008):5894-5900. |
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来源:中国科学院大学
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