Synthesis and crystal structure of a novel three-dimensional manganese(ii) coordination polymer: [mn(pdc)](n) (pdc = pyridine-2,4-dicarboxylate)
文献类型：期刊论文
| 作者 | Zhang Chun-Xia1,2; Ma Cheng-Bing1; Wang Mei1,2; Chen Chang-Neng1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:2页码:245-249 |
| 关键词 | Manganese complex Crystal structure 3-d network |
| ISSN号 | 0254-5861 |
| 通讯作者 | Chen chang-neng(ccn@fjirsm.ac.cn) |
| 英文摘要 | A novel manganese(ii) coordination polymer [mn(pdc)](n) (pdc = pyridine-2,4-dicarboxylate) has been synthesized under hydrothermal conditions. the crystal is of monoclinic, space group p2(1)/n with a = 6.506(4), b = 9.392(6), c = 11.217(7) angstrom, beta = 105.650(12)degrees, v = 660.0(7) angstrom(3), z = 4, m-r = 220.04, d-c = 2.215 g/cm(3), mu = 1.971 mm(-1), f(000) = 436, r-int = 0.0345, r = 0.0360 and wr = 0.0778 for 1259 observed reflections with i > 2 sigma(i). in the structure, the mn(ii) atom is coordinated in a distorted octahedral arrangement by one pyridine n and five carboxylate o atoms from five pdc ligands, each of which coordinates to five mn atoms to propagate a three-dimensional layered framework. |
| WOS关键词 | COMPLEXES |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000253179500024 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2390035 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen Chang-Neng |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Chun-Xia,Ma Cheng-Bing,Wang Mei,et al. Synthesis and crystal structure of a novel three-dimensional manganese(ii) coordination polymer: [mn(pdc)](n) (pdc = pyridine-2,4-dicarboxylate)[J]. Chinese journal of structural chemistry,2008,27(2):245-249. |
| APA | Zhang Chun-Xia,Ma Cheng-Bing,Wang Mei,&Chen Chang-Neng.(2008).Synthesis and crystal structure of a novel three-dimensional manganese(ii) coordination polymer: [mn(pdc)](n) (pdc = pyridine-2,4-dicarboxylate).Chinese journal of structural chemistry,27(2),245-249. |
| MLA | Zhang Chun-Xia,et al."Synthesis and crystal structure of a novel three-dimensional manganese(ii) coordination polymer: [mn(pdc)](n) (pdc = pyridine-2,4-dicarboxylate)".Chinese journal of structural chemistry 27.2(2008):245-249. |
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来源：中国科学院大学
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