Study of carbon-supported IrO2 and RuO2 for use in the hydrogen evolution reaction in a solid polymer electrolyte electrolyzer
文献类型：期刊论文
| 作者 | Cheng, Jinbin2; Zhang, Huamin1; Ma, Haipeng; Zhong, Hexiang; Zou, Yi |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2010-02-01 |
| 卷号 | 55期号:5页码:1855-1861 |
| 关键词 | Solid polymer electrolyte Water electrolysis Cathodic electrocatalyst Carbon-supported IrO2 Carbon-supported RuO2 |
| 产权排序 | 1;1 |
| 通讯作者 | 张华民 |
| 英文摘要 | carbon-supported iro2 and ruo2 were prepared using an incipient wetness method and were then calcinated at various temperatures. iro2/c and ruo2/c are less expensive than the conventional pt/c material and more stable than metal ni in an acidic electrolyte. moreover, iro2/c and ruo2/c are not influenced by under potential deposition (upd) and show lower sensitivity to poisoning by ni or fe impurities. the physical properties of iro2/c and ruo2/c were investigated via xrd and tem. cyclic voltammograms (cv) and tafel plots were used to provide information regarding surface redox reaction and electrocatalytic activity. the activity and durability of iro2/c and ruo2/c were studied after prolonged potential cycling between -0.3 and 0.3 v-sce. after comparison of tafel plots of pt/c and iro2/c after activation, it was observed that they have similar electrocatalytic activities in a hydrogen evolution reaction (her). a single cell test with solid polymer electrolyte (spe) proved that the performance of iro2/c (0.5 mg cm(-2)) was similar to that of pt/c (0.5 mg cm(-2)). (c) 2009 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | prepared ruthenium oxide ; water electrolysis ; fuel-cell ; electrocatalysis ; activation ; cathode ; technology ; composites ; catalysts ; dioxide |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000275596900050 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103527]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Grp 303, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Jinbin,Zhang, Huamin,Ma, Haipeng,et al. Study of carbon-supported IrO2 and RuO2 for use in the hydrogen evolution reaction in a solid polymer electrolyte electrolyzer[J]. electrochimica acta,2010,55(5):1855-1861. |
| APA | Cheng, Jinbin,Zhang, Huamin,Ma, Haipeng,Zhong, Hexiang,&Zou, Yi.(2010).Study of carbon-supported IrO2 and RuO2 for use in the hydrogen evolution reaction in a solid polymer electrolyte electrolyzer.electrochimica acta,55(5),1855-1861. |
| MLA | Cheng, Jinbin,et al."Study of carbon-supported IrO2 and RuO2 for use in the hydrogen evolution reaction in a solid polymer electrolyte electrolyzer".electrochimica acta 55.5(2010):1855-1861. |
入库方式： OAI收割
来源：大连化学物理研究所
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