High performance composite membranes with enhanced dimensional stability for use in PEMFC
文献类型:期刊论文
作者 | Dai, Hua1,2; Zhang, Huamin1; Zhong, Hexiang1; Li, Xianfeng1; Xiao, Shaohua1,2; Mai, Zhensheng1,2 |
刊名 | international journal of hydrogen energy
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出版日期 | 2010-05-01 |
卷号 | 35期号:9页码:4209-4214 |
关键词 | Sulfonated poly(sulfide sulfone) Sulfonated poly(phenylene sulfone) Composite membranes Dimensional stability Fuel cell performance |
产权排序 | 1;1 |
通讯作者 | 张华民 |
英文摘要 | sulfonated poly(sulfide sulfone) (spssf)/porous polytetrafluoroethylene (ptfe) reinforced composite membranes were prepared from a mixed solvent containing n-butanol and dmso. to improve their dimensional stability, spssf/ptfe membranes were further oxidized to obtain sulfonated poly(phenylene sulfone) (spso2)/ptfe composite membranes under an optimized h(2)o(2) oxidation procedure in acidic medium. thin composite membranes with good mechanical stability can be fabricated due to the ptfe reinforcement. sem and ftir indicated the sulfonated polymers were fully impregnated into the expanded ptfe. spso2/ptfe membranes show better thermal and dimensional stability than spssf/ptfe membranes. both composite membranes exhibited very excellent single cell performance. a maximum power density of 1.34 w cm(-2) for the spso2/ptfe membrane was obtained at 80 degrees c and 100 rh%. (c) 2010 professor t. nejat veziroglu. published by elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
关键词[WOS] | proton-exchange membranes ; fuel-cell applications ; poly(sulfide sulfone) ; low-temperature ; systems ; conductivity ; polyimides ; copolymers ; ionomers ; acid |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000277857600032 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/103535] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Dai, Hua,Zhang, Huamin,Zhong, Hexiang,et al. High performance composite membranes with enhanced dimensional stability for use in PEMFC[J]. international journal of hydrogen energy,2010,35(9):4209-4214. |
APA | Dai, Hua,Zhang, Huamin,Zhong, Hexiang,Li, Xianfeng,Xiao, Shaohua,&Mai, Zhensheng.(2010).High performance composite membranes with enhanced dimensional stability for use in PEMFC.international journal of hydrogen energy,35(9),4209-4214. |
MLA | Dai, Hua,et al."High performance composite membranes with enhanced dimensional stability for use in PEMFC".international journal of hydrogen energy 35.9(2010):4209-4214. |
入库方式: OAI收割
来源:大连化学物理研究所
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