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Preferential oxidation of co in h(2) rich stream over au/ceo(2)-co(3)o(4) catalysts

文献类型:期刊论文

作者Wang, Hui1,2; Zhu, Huaqing1; Qin, Zhangfeng1; Wang, Guofu1; Liang, Feixue1,2; Wang, Jianguo1
刊名Catalysis communications
出版日期2008-03-31
卷号9期号:6页码:1487-1492
关键词Preferential oxidation of co Prox Hydrogen rich stream Au/ceo(2)-co(3)o(4)
ISSN号1566-7367
DOI10.1016/j.catcom.2007.12.017
通讯作者Wang, jianguo(iccjgw@sxicc.ac.cn)
英文摘要Au/ceo(2)-co(3)o(4) catalysts with a ce/co atomic ratio from 0.1 to 0.6 were prepared by deposition-precipitation; their catalytic performance in preferential oxidation (prox) of co in h(2) rich stream was investigated. au/ceo(2)-co(3)o(4) exhibits much higher catalytic activity in co prox than au/co(3)o(4) and au/ceo(2); over au/ceo(2)-co(3)o(4), 100% co conversion with 7% selectivity to co(2) can be achieved even at ambient temperature. typically, for co prox at 80 degrees c over oxidation pretreated au/ceo(2)-co(3)o(4) (ce/co = 0.2), 91% co conversion and 51% selectivity to co(2) can last for 260 h. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词CARBON-MONOXIDE OXIDATION ; WATER-GAS SHIFT ; SELECTIVE OXIDATION ; LOW-TEMPERATURE ; H-2-RICH GAS ; FUEL-CELLS ; GOLD CATALYSTS ; HYDROGEN ; AU ; H2O
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000253961400094
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2390176
专题中国科学院大学
通讯作者Wang, Jianguo
作者单位1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang, Hui,Zhu, Huaqing,Qin, Zhangfeng,et al. Preferential oxidation of co in h(2) rich stream over au/ceo(2)-co(3)o(4) catalysts[J]. Catalysis communications,2008,9(6):1487-1492.
APA Wang, Hui,Zhu, Huaqing,Qin, Zhangfeng,Wang, Guofu,Liang, Feixue,&Wang, Jianguo.(2008).Preferential oxidation of co in h(2) rich stream over au/ceo(2)-co(3)o(4) catalysts.Catalysis communications,9(6),1487-1492.
MLA Wang, Hui,et al."Preferential oxidation of co in h(2) rich stream over au/ceo(2)-co(3)o(4) catalysts".Catalysis communications 9.6(2008):1487-1492.

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来源:中国科学院大学

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