The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions
文献类型：期刊论文
| 作者 | Zhao, D.1,2,3; Yi, B. L.1; Zhang, H. M.1; Liu, Meilin1,3 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2010-08-01 |
| 卷号 | 195期号:15页码:4606-4612 |
| 关键词 | Proton exchange membrane Degradation Durability Platinum deposition Free radicals Hydrogen peroxide |
| 产权排序 | 1;1 |
| 通讯作者 | 衣宝廉 |
| 英文摘要 | the effect of platinum on free radical generation and membrane degradation in proton exchange membrane (pem) fuel cells is investigated using three typical cell configurations. examinations of the fluoride emission rates (fers) under different testing conditions indicate that platinum deposited in the membrane plays an important role as a catalytic center for the formation of h(2)o(2) and ho(center dot) free radicals, leading to pem degradation. the chemical durability of the membranes is tested in accelerated fenton tests. it confirms the formation of free radicals in the presence of platinum in the decomposition of h(2)o(2) by colorimetric method with dimethyl sulfoxide (dmso) as the trapping agent. in addition, structural and morphological changes of the membranes are characterized using ft-ir spectroscopy and scanning electron microscopy (sem). crown copyright (c) 2010 published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | proton-exchange membrane ; standard addition method ; open-circuit operation ; degradation mechanism ; hydrogen-peroxide ; electrolyte membranes ; ionomer membranes ; acid ; pemfc ; decomposition |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000277820500007 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/103551]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Georgia Inst Technol, Sch Mat Sci Engn, Atlanta, GA 30332 USA |
| 推荐引用方式 GB/T 7714 | Zhao, D.,Yi, B. L.,Zhang, H. M.,et al. The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions[J]. journal of power sources,2010,195(15):4606-4612. |
| APA | Zhao, D.,Yi, B. L.,Zhang, H. M.,&Liu, Meilin.(2010).The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions.journal of power sources,195(15),4606-4612. |
| MLA | Zhao, D.,et al."The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions".journal of power sources 195.15(2010):4606-4612. |
入库方式： OAI收割
来源：大连化学物理研究所
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