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Chinese Academy of Sciences Institutional Repositories Grid
Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation

文献类型:期刊论文

作者Ahmadiannamini, Pejman1; Li, Xianfeng1,3; Goyens, Ward1; Meesschaert, Boudewijn1,2; Vankelecom, Ivo F. J.1
刊名journal of membrane science
出版日期2010-09-15
卷号360期号:1-2页码:250-258
关键词Nanofiltration Anion separation Multilayered polyelectrolyte membranes
产权排序3;2
通讯作者ivo f.j. vankelecom
英文摘要layer-by-layer (lbl) deposition of polyelectrolytes (pes) on porous substrates has emerged as a versatile and inexpensive method to form high flux nanofiltration (nf) membranes. pe complexes (pecs) were prepared by alternative deposition of poly(diallyldimethylammonium) chloride (pdda) and sulfonated poly(ether ether ketone) (speek) on hydrolyzed polyacrylonitrile (pan-h) supports. pdda/speek multilayers consisting of 5, 10, 15 and 20 bilayers were deposited from solutions with different nacl concentrations. film thickness was studied by afm. thicker films were formed with increasing the bilayer number and the salt concentration. for the first time, multilayered pdda/speek pec membranes were applied as nf membrane in an anion separation application. the nf performance of pdda/speek membranes was studied for single salt solutions (chloride, sulfate and phosphate) as well as mixed-salt (binary and ternary). membranes showed different retentions and fluxes for anions in single and mixed-salt solutions. when using mixed-salt solutions, the retentions were found to be higher compared to the single salt nf experiment results. hpo(4)(2-) ions showed a remarkable influence on the performance of the pec membranes via formation of intermolecular bonds within the polymer chains. in the best case, membranes showed cl(-)/so(4)(2-) and cl(-)/hpo(4)(2-) selectivities of 20 in the separation of mixed-salt solutions. (c) 2010 published by elsevier b.v.
WOS标题词science & technology ; technology ; physical sciences
类目[WOS]engineering, chemical ; polymer science
研究领域[WOS]engineering ; polymer science
关键词[WOS]weak polyelectrolytes ; system ; films ; deposition ; thickness ; removal ; charge ; water
收录类别SCI
原文出处false
语种英语
WOS记录号WOS:000280311500029
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/103553]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Katholieke Univ Leuven, Fac Bioengn Sci, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
2.Katholieke Univ Leuven, Dept Ind Sci & Technol, Katholieke Hogeschool Brugge Oostende, Fac Ind Sci, B-8400 Oostende, Belgium
3.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Ahmadiannamini, Pejman,Li, Xianfeng,Goyens, Ward,et al. Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation[J]. journal of membrane science,2010,360(1-2):250-258.
APA Ahmadiannamini, Pejman,Li, Xianfeng,Goyens, Ward,Meesschaert, Boudewijn,&Vankelecom, Ivo F. J..(2010).Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation.journal of membrane science,360(1-2),250-258.
MLA Ahmadiannamini, Pejman,et al."Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation".journal of membrane science 360.1-2(2010):250-258.

入库方式: OAI收割

来源:大连化学物理研究所

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