Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation
文献类型:期刊论文
作者 | Ahmadiannamini, Pejman1; Li, Xianfeng1,3; Goyens, Ward1; Meesschaert, Boudewijn1,2; Vankelecom, Ivo F. J.1 |
刊名 | journal of membrane science
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出版日期 | 2010-09-15 |
卷号 | 360期号:1-2页码:250-258 |
关键词 | Nanofiltration Anion separation Multilayered polyelectrolyte membranes |
产权排序 | 3;2 |
通讯作者 | ivo f.j. vankelecom |
英文摘要 | layer-by-layer (lbl) deposition of polyelectrolytes (pes) on porous substrates has emerged as a versatile and inexpensive method to form high flux nanofiltration (nf) membranes. pe complexes (pecs) were prepared by alternative deposition of poly(diallyldimethylammonium) chloride (pdda) and sulfonated poly(ether ether ketone) (speek) on hydrolyzed polyacrylonitrile (pan-h) supports. pdda/speek multilayers consisting of 5, 10, 15 and 20 bilayers were deposited from solutions with different nacl concentrations. film thickness was studied by afm. thicker films were formed with increasing the bilayer number and the salt concentration. for the first time, multilayered pdda/speek pec membranes were applied as nf membrane in an anion separation application. the nf performance of pdda/speek membranes was studied for single salt solutions (chloride, sulfate and phosphate) as well as mixed-salt (binary and ternary). membranes showed different retentions and fluxes for anions in single and mixed-salt solutions. when using mixed-salt solutions, the retentions were found to be higher compared to the single salt nf experiment results. hpo(4)(2-) ions showed a remarkable influence on the performance of the pec membranes via formation of intermolecular bonds within the polymer chains. in the best case, membranes showed cl(-)/so(4)(2-) and cl(-)/hpo(4)(2-) selectivities of 20 in the separation of mixed-salt solutions. (c) 2010 published by elsevier b.v. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | engineering, chemical ; polymer science |
研究领域[WOS] | engineering ; polymer science |
关键词[WOS] | weak polyelectrolytes ; system ; films ; deposition ; thickness ; removal ; charge ; water |
收录类别 | SCI |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000280311500029 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/103553] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Katholieke Univ Leuven, Fac Bioengn Sci, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium 2.Katholieke Univ Leuven, Dept Ind Sci & Technol, Katholieke Hogeschool Brugge Oostende, Fac Ind Sci, B-8400 Oostende, Belgium 3.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Ahmadiannamini, Pejman,Li, Xianfeng,Goyens, Ward,et al. Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation[J]. journal of membrane science,2010,360(1-2):250-258. |
APA | Ahmadiannamini, Pejman,Li, Xianfeng,Goyens, Ward,Meesschaert, Boudewijn,&Vankelecom, Ivo F. J..(2010).Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation.journal of membrane science,360(1-2),250-258. |
MLA | Ahmadiannamini, Pejman,et al."Multilayered PEC nanofiltration membranes based on SPEEK/PDDA for anion separation".journal of membrane science 360.1-2(2010):250-258. |
入库方式: OAI收割
来源:大连化学物理研究所
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