中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Dsc study of stabilization reactions in poly(acrylo-nitrile-co-itaconic acid) with peak-resolving method

文献类型:期刊论文

作者Ouyang, Q.1,2; Cheng, L.1,2; Wang, H. J.1; Li, K. X.1
刊名Journal of thermal analysis and calorimetry
出版日期2008-10-01
卷号94期号:1页码:85-88
ISSN号1388-6150
关键词Dsc Pan Peak-resolving method Poly(acrylonitrile-co-itaconic acid) Stabilization
DOI10.1007/s10973-007-8773-5
通讯作者Wang, h. j.(hjwang@sxicc.ac.cn)
英文摘要The effect of itaconic acid (ia) content and heating rate on the stabilization reactions in poly(acrylonitrile-co-itaconic acid) (p(an-co-ia)) was investigated by differential scanning calorimetry (dsc) with peak-resolving method. increasing ia content was effective in decreasing the initial temperature and the heat evolved, and found to enhance oxidative reactions to some extent. while, promoting heating rate resulted in a shift of the exotherm to a higher temperature and a more rapid liberation of heat. the percentage of area of the first exothermic peak increased with increasing heating rate, which would be attributed to the enhancement of the free radical cyclization reactions.
WOS关键词ITACONIC ACID ; THERMAL-BEHAVIOR ; ACRYLONITRILE ; POLYACRYLONITRILE ; COMONOMER ; DIMETHYLFORMAMIDE ; COPOLYMERIZATION
WOS研究方向Chemistry
WOS类目Chemistry, Analytical ; Chemistry, Physical
语种英语
出版者SPRINGER
WOS记录号WOS:000260114000013
URI标识http://www.irgrid.ac.cn/handle/1471x/2390412
专题中国科学院大学
通讯作者Wang, H. J.
作者单位1.Chinese Acad Sci, Shanxi Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ouyang, Q.,Cheng, L.,Wang, H. J.,et al. Dsc study of stabilization reactions in poly(acrylo-nitrile-co-itaconic acid) with peak-resolving method[J]. Journal of thermal analysis and calorimetry,2008,94(1):85-88.
APA Ouyang, Q.,Cheng, L.,Wang, H. J.,&Li, K. X..(2008).Dsc study of stabilization reactions in poly(acrylo-nitrile-co-itaconic acid) with peak-resolving method.Journal of thermal analysis and calorimetry,94(1),85-88.
MLA Ouyang, Q.,et al."Dsc study of stabilization reactions in poly(acrylo-nitrile-co-itaconic acid) with peak-resolving method".Journal of thermal analysis and calorimetry 94.1(2008):85-88.

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来源:中国科学院大学

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