Hydrothermal synthesis, crystal structure and magnetic property of a novel mixed valence decatungstate: [cu(2,2 '-bipy)(2)](2)(na2w6w4o30)-w-v-o-vi center dot 2h(2)o
文献类型：期刊论文
| 作者 | Li Tao-Hai1,2; Lue Tao-Hai1,2; Gao Shui-Ying1; Cao Rong1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:1页码:57-62 |
| 关键词 | Crystal structure Decatungstate Mixed valence Magnetic property |
| ISSN号 | 0254-5861 |
| 通讯作者 | Cao rong(rcao@fjirsm.ac.cn) |
| 英文摘要 | A novel cu(ii)-2,2'-bipy-supported (bipy = bipyridine) mixed valence decatungstate, [cu(2,2'-bipy)(2)](2)(na2w6w4o30)-w-v-o-vi center dot 2h(2)o 1, has been synthesized and structurally characterized by x-ray analysis. the crystal of 1 is of triclinic, space group p (1) over bar with a = 10.9393(10), b = 12.0492(2), c = 12.3783(2) angstrom, a = 80.631(10), beta = 70.226(10), gamma= 72.329(9)degrees, v = 1459.64(4) angstrom(3), z = 1, d-c = 3.582 g/cm(3), f(000) = 1404, r = 0.0553 and wr = 0.1242 for 4607 observed reflections (i > 2 sigma(i)). the epr spectrum of 1 indicates that its unpaired electrons are placed in the d(x2-y2) orbital of the ground state of cu-ii. furthermore, compound 1 shows an antiferromagnetic interaction. |
| WOS关键词 | POLYOXOMETALATE ; CLUSTERS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000253026300010 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2390475 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao Rong |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Tao-Hai,Lue Tao-Hai,Gao Shui-Ying,et al. Hydrothermal synthesis, crystal structure and magnetic property of a novel mixed valence decatungstate: [cu(2,2 '-bipy)(2)](2)(na2w6w4o30)-w-v-o-vi center dot 2h(2)o[J]. Chinese journal of structural chemistry,2008,27(1):57-62. |
| APA | Li Tao-Hai,Lue Tao-Hai,Gao Shui-Ying,&Cao Rong.(2008).Hydrothermal synthesis, crystal structure and magnetic property of a novel mixed valence decatungstate: [cu(2,2 '-bipy)(2)](2)(na2w6w4o30)-w-v-o-vi center dot 2h(2)o.Chinese journal of structural chemistry,27(1),57-62. |
| MLA | Li Tao-Hai,et al."Hydrothermal synthesis, crystal structure and magnetic property of a novel mixed valence decatungstate: [cu(2,2 '-bipy)(2)](2)(na2w6w4o30)-w-v-o-vi center dot 2h(2)o".Chinese journal of structural chemistry 27.1(2008):57-62. |
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来源：中国科学院大学
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