A novel effective way of comprising a beta-nucleating agent in isotactic polypropylene (i-pp): polymerized dispersion and polymer characterization
文献类型：期刊论文
| 作者 | Yi, Qing-Feng1,2,3; Wen, Xiao-Fing1,2,3; Dong, Jin-Yong1,2; Han, Charles C.1,2 |
| 刊名 | Polymer
 |
| 出版日期 | 2008-10-30 |
| 卷号 | 49期号:23页码:5053-5063 |
| ISSN号 | 0032-3861 |
| 关键词 | Beta-nucleating agent Polypropylene Polymerized dispersion |
| DOI | 10.1016/j.polymer.2008.09.037 |
| 通讯作者 | Dong, jin-yong(jydong@iccas.ac.cn) |
| 英文摘要 | A kind of beta-nucleating agent, namely a stearic acid and stearate lanthanum complex (na beta), was introduced into isotactic polypropylene (i-pp) via an in situ polymerization method for the first time. a dynamic adhesion model was constructed for interpreting the beta-nucleating agent dispersion process. the effects of a polymerized dispersion of the beta-nucleating agent on the content of beta-crystal and crystallization behavior of i-pp were investigated. the results show that the crystallization peak temperature of thus beta-nucleated i-pp was greatly increased while the spherulite size dramatically decreased compared with those of net i-pr the content of beta-phase (k(beta) value) can reach as high as 88.7% with only 0.135 wt% of na beta addition, which holds constant with a further increase of na beta concentration up to 3.41 wt%. the non-isothermal crystallization kinetics of thus beta-nucleated i-pp was studied with mo equation and crystallization activation energy estimated by kissinger method, giving unique results pertaining to the unprecedented nap polymerized dispersion. (c) 2008 elsevier ltd. all rights reserved. |
| WOS关键词 | FLOW-INDUCED CRYSTALLIZATION ; X-RAY-DIFFRACTION ; PHASE ; SHEAR ; BEHAVIOR ; MICROSCOPY ; MORPHOLOGY ; FORM ; ORIENTATION ; TEMPERATURE |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000260599400019 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2390810 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Dong, Jin-Yong |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, Qing-Feng,Wen, Xiao-Fing,Dong, Jin-Yong,et al. A novel effective way of comprising a beta-nucleating agent in isotactic polypropylene (i-pp): polymerized dispersion and polymer characterization[J]. Polymer,2008,49(23):5053-5063. |
| APA | Yi, Qing-Feng,Wen, Xiao-Fing,Dong, Jin-Yong,&Han, Charles C..(2008).A novel effective way of comprising a beta-nucleating agent in isotactic polypropylene (i-pp): polymerized dispersion and polymer characterization.Polymer,49(23),5053-5063. |
| MLA | Yi, Qing-Feng,et al."A novel effective way of comprising a beta-nucleating agent in isotactic polypropylene (i-pp): polymerized dispersion and polymer characterization".Polymer 49.23(2008):5053-5063. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。