Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-kappa n-2,n ')cobalt(ii) dichloromethane hemisolvate
文献类型：期刊论文
| 作者 | Yang, Yue1,2; Yang, Peiju1; Zhang, Cui1,2; Wu, Biao1 |
| 刊名 | Acta crystallographica section e-structure reports online
 |
| 出版日期 | 2008-05-01 |
| 卷号 | 64页码:M623-u183 |
| ISSN号 | 1600-5368 |
| DOI | 10.1107/s1600536808007320 |
| 通讯作者 | Wu, biao(wubiao@lzb.ac.cn) |
| 英文摘要 | The title compound, [cocl2(c21h17cln2)]center dot 0.5ch(2)cl(2), crystallizes from dichloromethane as a 2:1 solvate [cocl2l](2)center dot ch2cl2 (l is 2-chloro-9-mesityl-1,10-phenanthroline). there are two independent cocl2l molecules in the asymmetric unit and both molecules have similar conformations. they are connected by a weak c-h center dot center dot center dot pi interaction involving the mesityl ring. the cobalt center is four-coordinated by the two n-atom donors of the bidentate ligand and two chloride ions in a distorted tetrahedral geometry. the packing of the molecules is stabilized by weak slipped pi-pi stacking interactions between symmetry-related phenanthroline groups. |
| WOS关键词 | CATALYSTS ; IRON |
| WOS研究方向 | Crystallography |
| WOS类目 | Crystallography |
| 语种 | 英语 |
| 出版者 | BLACKWELL PUBLISHING |
| WOS记录号 | WOS:000255450100018 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2391228 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Biao |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Sysnth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yue,Yang, Peiju,Zhang, Cui,et al. Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-kappa n-2,n ')cobalt(ii) dichloromethane hemisolvate[J]. Acta crystallographica section e-structure reports online,2008,64:M623-u183. |
| APA | Yang, Yue,Yang, Peiju,Zhang, Cui,&Wu, Biao.(2008).Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-kappa n-2,n ')cobalt(ii) dichloromethane hemisolvate.Acta crystallographica section e-structure reports online,64,M623-u183. |
| MLA | Yang, Yue,et al."Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-kappa n-2,n ')cobalt(ii) dichloromethane hemisolvate".Acta crystallographica section e-structure reports online 64(2008):M623-u183. |
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来源：中国科学院大学
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