Synthesis and characterization of two linear trinuclear complexes [m-3(ch3coo)(6)(h2o)(phen)(2)]center dot h2o (m = co, mn)
文献类型：期刊论文
| 作者 | Wang, Mei1,2; Ma, Cheng-Bing1; Wang, Hui-Sheng1,2; Chen, Chang-Neng1; Liu, Qiu-Tian1 |
| 刊名 | Journal of molecular structure
 |
| 出版日期 | 2008-02-17 |
| 卷号 | 873期号:1-3页码:94-100 |
| 关键词 | Cobalt(ii) Manganese(ii) Linear trinuclear compounds Crystal structure Magnetic properties |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2007.03.011 |
| 通讯作者 | Chen, chang-neng(ccn@fjirsm.ac.cn) |
| 英文摘要 | Two linear trinuclear compounds [co-3(ch3coo)(6)(h2o)(phen)(2)] center dot h2o 1 and [mn-3(ch3coo)(6)(h2o)(phen)(2)] center dot h2o (phen = 1, 10-phenanthroline) 2 have been synthesized and characterized by single crystal x-ray diffraction, ir spectroscopy, thermal analysis and magnetic measurements. the x-ray analyses of 1 and 2 show that the two compounds have the same coordination environment but different central metal ions (co(ii) and mn(ii), respectively). the structures of 1 and 2 both consist of a trinuclear cobalt/manganese unit coordinated by two terminal phen groups, one h2o on the central co(ii)/mn(ii) and six ch3coo- groups featuring four kinds of bonding mode. the magnetic measurements of the two complexes reveal overall antiferromagnetic exchange interactions between the metal ions. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | CRYSTAL-STRUCTURE ; COORDINATION POLYMERS ; CARBOXYLATE COMPLEXES ; MANGANESE CLUSTER ; OXIDATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000253291900013 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392196 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Chang-Neng |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Mei,Ma, Cheng-Bing,Wang, Hui-Sheng,et al. Synthesis and characterization of two linear trinuclear complexes [m-3(ch3coo)(6)(h2o)(phen)(2)]center dot h2o (m = co, mn)[J]. Journal of molecular structure,2008,873(1-3):94-100. |
| APA | Wang, Mei,Ma, Cheng-Bing,Wang, Hui-Sheng,Chen, Chang-Neng,&Liu, Qiu-Tian.(2008).Synthesis and characterization of two linear trinuclear complexes [m-3(ch3coo)(6)(h2o)(phen)(2)]center dot h2o (m = co, mn).Journal of molecular structure,873(1-3),94-100. |
| MLA | Wang, Mei,et al."Synthesis and characterization of two linear trinuclear complexes [m-3(ch3coo)(6)(h2o)(phen)(2)]center dot h2o (m = co, mn)".Journal of molecular structure 873.1-3(2008):94-100. |
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来源：中国科学院大学
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