Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii
文献类型:期刊论文
作者 | Ma, Maoxia1,2; Yang, Chongren1; Zhang, Yingjun1 |
刊名 | Magnetic resonance in chemistry
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出版日期 | 2008-06-01 |
卷号 | 46期号:6页码:571-575 |
关键词 | Nmr 1d/2d nmr Polyhydroxylated ursolic acids Epimer Dischidia esquirolii Asclepiadaceae |
ISSN号 | 0749-1581 |
DOI | 10.1002/mrc.2212 |
通讯作者 | Zhang, yingjun(zhangyj@mail.kib.ac.cn) |
英文摘要 | The complete assignments of all the (1)h and (13)c nmr signals of three polyhydroxylated 12-ursen-type triterpenes, 6 beta,19 alpha,22 alpha-trihydroxyurs-12-en-3-oxo-28-oic acid (1), 3 beta,6 alpha,19 alpha,23-tetrahydroxyurs-12-en-28-oic acid (2) and 3 beta,6 beta,19 alpha,23-tetrahydroxyurs-12-en-28-oic acid (3), were carried out by means of homo- and hetero-nuclear two-dimensional nmr experiments. compounds 1-3 were isolated from the aerial parts of dischidia esquirolii. of them, 1 and 2 were identified as new polyhydroxylated ursolic acid derivatives. compound 2 is the c-6 hydroxyl epimer of 3, which was isolated first from adina rubella, and its structure is revised in this paper. copyright (c) 2008 john wiley & sons, ltd. |
WOS关键词 | UNCARIA-TOMENTOSA ; CONSTITUENTS ; GLYCOSIDES ; PLANTS |
WOS研究方向 | Chemistry ; Spectroscopy |
WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Spectroscopy |
语种 | 英语 |
WOS记录号 | WOS:000256492000010 |
出版者 | WILEY-BLACKWELL |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392400 |
专题 | 中国科学院大学 |
通讯作者 | Zhang, Yingjun |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Maoxia,Yang, Chongren,Zhang, Yingjun. Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii[J]. Magnetic resonance in chemistry,2008,46(6):571-575. |
APA | Ma, Maoxia,Yang, Chongren,&Zhang, Yingjun.(2008).Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii.Magnetic resonance in chemistry,46(6),571-575. |
MLA | Ma, Maoxia,et al."Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii".Magnetic resonance in chemistry 46.6(2008):571-575. |
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来源:中国科学院大学
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