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Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii

文献类型:期刊论文

作者Ma, Maoxia1,2; Yang, Chongren1; Zhang, Yingjun1
刊名Magnetic resonance in chemistry
出版日期2008-06-01
卷号46期号:6页码:571-575
关键词Nmr 1d/2d nmr Polyhydroxylated ursolic acids Epimer Dischidia esquirolii Asclepiadaceae
ISSN号0749-1581
DOI10.1002/mrc.2212
通讯作者Zhang, yingjun(zhangyj@mail.kib.ac.cn)
英文摘要The complete assignments of all the (1)h and (13)c nmr signals of three polyhydroxylated 12-ursen-type triterpenes, 6 beta,19 alpha,22 alpha-trihydroxyurs-12-en-3-oxo-28-oic acid (1), 3 beta,6 alpha,19 alpha,23-tetrahydroxyurs-12-en-28-oic acid (2) and 3 beta,6 beta,19 alpha,23-tetrahydroxyurs-12-en-28-oic acid (3), were carried out by means of homo- and hetero-nuclear two-dimensional nmr experiments. compounds 1-3 were isolated from the aerial parts of dischidia esquirolii. of them, 1 and 2 were identified as new polyhydroxylated ursolic acid derivatives. compound 2 is the c-6 hydroxyl epimer of 3, which was isolated first from adina rubella, and its structure is revised in this paper. copyright (c) 2008 john wiley & sons, ltd.
WOS关键词UNCARIA-TOMENTOSA ; CONSTITUENTS ; GLYCOSIDES ; PLANTS
WOS研究方向Chemistry ; Spectroscopy
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Spectroscopy
语种英语
WOS记录号WOS:000256492000010
出版者WILEY-BLACKWELL
URI标识http://www.irgrid.ac.cn/handle/1471x/2392400
专题中国科学院大学
通讯作者Zhang, Yingjun
作者单位1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ma, Maoxia,Yang, Chongren,Zhang, Yingjun. Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii[J]. Magnetic resonance in chemistry,2008,46(6):571-575.
APA Ma, Maoxia,Yang, Chongren,&Zhang, Yingjun.(2008).Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii.Magnetic resonance in chemistry,46(6),571-575.
MLA Ma, Maoxia,et al."Complete assignments of (1)h and (13)c nmr spectral data for three polyhydroxylated 12-ursen-type triterpenoids from dischidia esquirolii".Magnetic resonance in chemistry 46.6(2008):571-575.

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来源:中国科学院大学

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