Liquid phase oxidation reactions catalyzed by polyoxometalates
文献类型：期刊论文
| 作者 | Lang Xianjun1,2; Lu Ruiling1,2; Li Zhen1; Xia Chungu1 |
| 刊名 | Progress in chemistry
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 20期号:4页码:469-482 |
| 关键词 | Polyoxometalates Clean oxidation Hydrogen peroxide Molecular oxygen Biomimetic catalysis |
| ISSN号 | 1005-281X |
| 通讯作者 | Lang xianjun() |
| 英文摘要 | After a brief introduction to the structure and general properties of polyoxometalates, the unusual versatility and tunability and their compatibility with environmentally and economically attractive conditions (solvents, oxidants, etc.) are outlined. these characteristics enable polyoxometalates suitable for catalyst to design at the atomic/molecular levels and applicable in the aspects of green catalysis and clean production. recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized. the emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively. the oxidation mechanisms are elucidated in detail. in addition, the applications of polyoxometalates in the area of biomimetic catalysis are discussed. |
| WOS关键词 | AQUEOUS HYDROGEN-PEROXIDE ; VANADIUM-SUBSTITUTED HETEROPOLYMOLYBDATES ; MANGANESE-CONTAINING POLYOXOMETALATE ; HIGHLY EFFICIENT UTILIZATION ; CHIRAL ALLYLIC ALCOHOLS ; RAY CRYSTAL-STRUCTURES ; ATM MOLECULAR-OXYGEN ; SELECTIVE EPOXIDATION ; AEROBIC OXIDATION ; H5PV2MO10O40 POLYOXOMETALATE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000255239400006 |
| 出版者 | CHINESE ACAD SCIENCES |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392463 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Lang Xianjun |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synthesis & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lang Xianjun,Lu Ruiling,Li Zhen,et al. Liquid phase oxidation reactions catalyzed by polyoxometalates[J]. Progress in chemistry,2008,20(4):469-482. |
| APA | Lang Xianjun,Lu Ruiling,Li Zhen,&Xia Chungu.(2008).Liquid phase oxidation reactions catalyzed by polyoxometalates.Progress in chemistry,20(4),469-482. |
| MLA | Lang Xianjun,et al."Liquid phase oxidation reactions catalyzed by polyoxometalates".Progress in chemistry 20.4(2008):469-482. |
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来源：中国科学院大学
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