Supramolecular assemblies formed by cooperative metal coordination and dimerization of the n-(2-pyirimidyl)-n '-(3-pyridyl)urea ligand via hydrogen bonding
文献类型：期刊论文
| 作者 | Jia, Chuandong1,3; Liang, Jianjun1; Yang, Jin2; Huang, Xiaojuan1; Yang, Xiao-Juan1,2; Wu, Biao1,2; Tang, Ning2 |
| 刊名 | Zeitschrift fur anorganische und allgemeine chemie
 |
| 出版日期 | 2008 |
| 卷号 | 634期号:6-7页码:1210-1214 |
| 关键词 | N-(2-pyrimidyl)-n'-(3-pyridyl)urea Supramolecular structure Hydrogen bonding Cobalt Zinc |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.200800041 |
| 通讯作者 | Wu, biao(wubiao@lzb.ac.cn) |
| 英文摘要 | The supramolecular structures of two metal complexes, [cocl2l2] (1) and [zncl2l2] (2), where l = n-(2-pyrimidyl)-n'-(3-pyridyl)urea, are reported. the complexes feature zigzag chains formed by the self-dimerization of the ligand via a pair of n-urea-h center dot center dot center dot n-pyrimidyl hydrogen bonds with the r-2(2)(8) motif. only the pyridyl nitrogen atom coordinates to the metal atom whereas the two pyrimidyl n donors are involved in intra- and intermolecular hydrogen bonding interactions. the coordinated cl atoms do not form any hydrogen bonds with the urea nh groups. the dimerization of the ligand (k = 90 m-1) was investigated by h-1 nmr spectroscopy. |
| WOS关键词 | CRYSTAL-STRUCTURES ; ORGANIC FRAMEWORK ; ANION-BINDING ; UREA ; COMPLEXES ; POLYMERS ; STACKING ; NETWORKS ; SYNTHON ; NITRATE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000256172500042 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392592 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Biao |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China 3.Grad Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Chuandong,Liang, Jianjun,Yang, Jin,et al. Supramolecular assemblies formed by cooperative metal coordination and dimerization of the n-(2-pyirimidyl)-n '-(3-pyridyl)urea ligand via hydrogen bonding[J]. Zeitschrift fur anorganische und allgemeine chemie,2008,634(6-7):1210-1214. |
| APA | Jia, Chuandong.,Liang, Jianjun.,Yang, Jin.,Huang, Xiaojuan.,Yang, Xiao-Juan.,...&Tang, Ning.(2008).Supramolecular assemblies formed by cooperative metal coordination and dimerization of the n-(2-pyirimidyl)-n '-(3-pyridyl)urea ligand via hydrogen bonding.Zeitschrift fur anorganische und allgemeine chemie,634(6-7),1210-1214. |
| MLA | Jia, Chuandong,et al."Supramolecular assemblies formed by cooperative metal coordination and dimerization of the n-(2-pyirimidyl)-n '-(3-pyridyl)urea ligand via hydrogen bonding".Zeitschrift fur anorganische und allgemeine chemie 634.6-7(2008):1210-1214. |
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来源：中国科学院大学
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