Synthesis, spectroscopic properties and electrochemistry of (2,9,16,23-tetrasubstituted phthalocyaninato) erbium complexes
文献类型：期刊论文
| 作者 | Bo, Shuhui; Tang, Daihua; Liu, Xinhou; Zhen, Zhen |
| 刊名 | Dyes and pigments
 |
| 出版日期 | 2008 |
| 卷号 | 76期号:1页码:35-40 |
| 关键词 | Lanthanide complexes Phthalocyanines Erbium Acetylacetone Sandwich |
| ISSN号 | 0143-7208 |
| DOI | 10.1016/j.dyepig.2006.08.030 |
| 通讯作者 | Zhen, zhen(zhenzhen@mail.ipc.ac.cn) |
| 英文摘要 | Two homoleptic bis(phthalocyaninato) erbium(iii) complexes er[pc(beta-or/r)(4)](2) and two half-sandwich phthalocyaninato erbium(iii) complexes (acac)er[pc(beta-or/r)(4)] (or = 1-n-pentyloxy and r = tert-butyl) have been synthesized and characterized by maldi-tof-ms as well as by various spectroscopic methods. the introduction of different substituents (alkoxy or alkyl groups) to the phthalocyanine rings induced changes in the spectroscopic and electrochemical properties. although the excited states of the homoleptic double- and triple-decker complexes usually are considered to lack fluorescence, in these cases, the homoleptic bis(phthalocyaninato) erbium(iii) complexes er[pc(beta-or/r)(4)](2) displayed intense fluorescence compared with the half-sandwich phthalocyaninato erbium(111) complexes (acac)er[pc(beta-or/r)(4)]. for the two kinds of phthalocyaninato erbium(iii) complexes, the pentyloxy-substituted complexes gave relatively intense emission compared with the tert-butylsubstituted complexes. these differences in the electronic ground state absorptions and in the excited state properties correlate with observations made from electrochemical measurements. (c) 2006 elsevier ltd. all rights reserved. |
| WOS关键词 | DOUBLE-DECKER COMPLEXES ; LANTHANIDE COMPLEXES ; SANDWICH COMPLEXES ; LIGANDS |
| WOS研究方向 | Chemistry ; Engineering ; Materials Science |
| WOS类目 | Chemistry, Applied ; Engineering, Chemical ; Materials Science, Textiles |
| 语种 | 英语 |
| WOS记录号 | WOS:000250079800006 |
| 出版者 | ELSEVIER SCI LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392617 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhen, Zhen |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Lab Organ Optoelect Funct Mat & Mol Engn, Beijing 100080, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bo, Shuhui,Tang, Daihua,Liu, Xinhou,et al. Synthesis, spectroscopic properties and electrochemistry of (2,9,16,23-tetrasubstituted phthalocyaninato) erbium complexes[J]. Dyes and pigments,2008,76(1):35-40. |
| APA | Bo, Shuhui,Tang, Daihua,Liu, Xinhou,&Zhen, Zhen.(2008).Synthesis, spectroscopic properties and electrochemistry of (2,9,16,23-tetrasubstituted phthalocyaninato) erbium complexes.Dyes and pigments,76(1),35-40. |
| MLA | Bo, Shuhui,et al."Synthesis, spectroscopic properties and electrochemistry of (2,9,16,23-tetrasubstituted phthalocyaninato) erbium complexes".Dyes and pigments 76.1(2008):35-40. |
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来源：中国科学院大学
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