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Synthesis and characterization of color-stable electroluminescent polymers: poly(dinaphtho [1,2-a : 1 ',2 '-g]-s-indacene)s

文献类型:期刊论文

作者Guo, Xin1,2; Yao, Bing1; Jiang, Guoxin1,2; Cheng, Yanxiang1; Xie, Zhiyuan1; Wang, Lixiang1; Ing, Xiabin1; Wang, Fosong1
刊名Journal of polymer science part a-polymer chemistry
出版日期2008-07-15
卷号46期号:14页码:4866-4878
关键词Color stability Conjugated polymers Light-emitting diodes Luminescence
ISSN号0887-624X
DOI10.1002/pola.22821
通讯作者Xie, zhiyuan(xiezy-n@ciac.jl.cn)
英文摘要Two new stepladder conjugated polymers, that is, poly(7,7,15,15-tetraoctyldinaphtho[1,2-a:1',2'-g]-s-indacene) (ponsi) and poly(7,7,15,15-tetra(4-octylphenyl)dinaphtho[1,2-a:1',2'-g]-s-indacene) (pansi) with alkyl and aryl substituents, respectively, have been synthesized and characterized. in comparison with poly(indenofluorene)s, both polymers have extended conjugation at the direction perpendicular to the polymer backbone because of the introduction of naphthalene moieties. the emission color of the polymers in film state is strongly dependent on the substituents. while ponsi emits at a maximum of 463 nm, pansi with the same backbone but aryl substituents displays dramatically redshifted emission with a maximum at 494 nm. both polymers show stable photoluminescence spectra while annealing at 200 degrees c in inert atmosphere. the ponsi-based devices with the configuration of ito/pedot:pss/polymer/ca/al turn on at 3.7 v, and emit at a maximum of 461 run with the cie coordinates of (0.19, 0.26), a maximum luminance efficiency of 1.40 cd/a, and a maximum brightness of 2036 cd/m(2) at 13 v meanwhile, the emission color of the devices is independent of driving voltage and keeps unchanged during the continuous operation. (c) 2008 wiley periodicals, inc.
WOS关键词LIGHT-EMITTING POLYMER ; CONJUGATED POLYMERS ; WHITE ELECTROLUMINESCENCE ; POLYFLUORENE DERIVATIVES ; SINGLE POLYMER ; BLUE EMISSION ; SIDE-CHAINS ; PHOTOPHYSICS ; EFFICIENCY ; STABILITY
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000257521600022
出版者JOHN WILEY & SONS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2392675
专题中国科学院大学
通讯作者Xie, Zhiyuan
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Guo, Xin,Yao, Bing,Jiang, Guoxin,et al. Synthesis and characterization of color-stable electroluminescent polymers: poly(dinaphtho [1,2-a : 1 ',2 '-g]-s-indacene)s[J]. Journal of polymer science part a-polymer chemistry,2008,46(14):4866-4878.
APA Guo, Xin.,Yao, Bing.,Jiang, Guoxin.,Cheng, Yanxiang.,Xie, Zhiyuan.,...&Wang, Fosong.(2008).Synthesis and characterization of color-stable electroluminescent polymers: poly(dinaphtho [1,2-a : 1 ',2 '-g]-s-indacene)s.Journal of polymer science part a-polymer chemistry,46(14),4866-4878.
MLA Guo, Xin,et al."Synthesis and characterization of color-stable electroluminescent polymers: poly(dinaphtho [1,2-a : 1 ',2 '-g]-s-indacene)s".Journal of polymer science part a-polymer chemistry 46.14(2008):4866-4878.

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