Establishment and application of the analysis method of pbdd/fs and pcdd/fs with isotope dilution high rosolution gas chromatography-high resolation mass spectrometry in ambient air samples
文献类型：期刊论文
| 作者 | Li Hui-Ru1,2; Yu Li-Ping1,2; Zhang Su-Kun1,2; Man, Ren1; Sheng Guo-Ying1; Fu Jia-Mo1; Peng Ping-An1 |
| 刊名 | Chinese journal of analytical chemistry
 |
| 出版日期 | 2008-02-01 |
| 卷号 | 36期号:2页码:150-156 |
| 关键词 | Dioxins Furans Polychloroinated dibenzo-p-dioxins/furans (pcdd/fs) polybrominated dibenzo-p-dioxins/furans (pbdd/fs) High resolution gas chromatography-high resolution mass spectrometry (hrgc-hrms) |
| ISSN号 | 0253-3820 |
| 通讯作者 | Li hui-ru() |
| 英文摘要 | It has been known that polybrominated dibenzo-p-dioxins/furans (pbdd/fs) share similar or even higher toxicity and bio-accumulativity with polychlorinated dibenzo-p-dioxins/furans (pcdd/fs). in this study, co-analysis method of pbdd/fs and pcdd/fs with isotope dilution high rosolution gas chromatography-high resolation mass spectrometry (hrgc-hrms) was built up based on u. s. epa method 1613 and method to-9a. the samples were exacted and cleaned through acid silica bed, multi-layer silica column and florisil column respectively. the last eluent was concentrated under gentle nitrogen gas flow and spiked with the injection internal standards of pbdd/fs and pcdd/fs. eight congeners of 2,3,7,8-pbdd/fs and 17 congeners of 2,3,7,8-pcdd/fs were quantified. the hrgc-hrms analysis condition for pbdd/fs was: ei(+) and sim model with the resolution >= 10000, the electron emission energy was 50 ev and the filament current was 0.75 ma; db-5 ms fused silica capillary column (60 in x 0.25 mm 1.d., 0.25 mu m); the temperatures of injection, ion source and transfer line were 250 degrees c, 250 degrees c and 305 degrees c, respectively. the carrier gas was helium with the flow 1.0 ml/min. the results showed that the relative standard deviation (rsd) of parallel blank samples was <= 10. 3 % and the recovery of pbdd/fs and pcdd/fs was in the range of 73 % 112%. average quantified values of standard reference sample were in accordance with the certified values and rsd were <=: 12.0%. the method detection limits were: tetrabromodibenzofuran ( tbdf), 0.25 pg/l; tebrachlorodibenzo-dioxin (tbdd), 0.3 pg/mu l; pentabromodibenzo-furans (pebdfs), 0.5 pg/mu l; pentabromodibenzo-,b-dioxin (pebdds), 1.0 pg/mu l; hexabromodibenzo-p-dioxin/furans (hxbdd/fs), 1.5 pg/mu l; tetrachlorodibenzo-p-dioxin/furan (tcdd/fs), 0.5 pg/mu l; pentachlorodibenzodioxin/furans (pecdd/fs) and hexachlorodibenzodioxin/furans (hxcdd/fs), 2.5 pg/mu l; heptachlorodibenzo-p-dioxin/furans (hpcdd/fs) and octachlorodibenzo-p-dioxin/furans (ocdd/fs), 5 pg/mu l. concentrations of pbdd/fs and pcdd/fs in the atmospheric particulate samples of a certain area were 1.01 -2. 43 pg/m(3) and 6.19 - 10. 8 pg/m(3), and gaseous samples were 0.036 - 0. 801 pg/m(3) and 1. 37 - 12. 1 pg/m(3) respectively. compared with other areas in the world, the atmospheric dioxins pollution of the sampling area was at high level. |
| WOS关键词 | DIBENZO-P-DIOXINS ; DEPOSITION ; PBDF |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000254252200003 |
| 出版者 | ELSEVIER SCIENCE INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2392688 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li Hui-Ru |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Key Lab Environm & Resources, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Hui-Ru,Yu Li-Ping,Zhang Su-Kun,et al. Establishment and application of the analysis method of pbdd/fs and pcdd/fs with isotope dilution high rosolution gas chromatography-high resolation mass spectrometry in ambient air samples[J]. Chinese journal of analytical chemistry,2008,36(2):150-156. |
| APA | Li Hui-Ru.,Yu Li-Ping.,Zhang Su-Kun.,Man, Ren.,Sheng Guo-Ying.,...&Peng Ping-An.(2008).Establishment and application of the analysis method of pbdd/fs and pcdd/fs with isotope dilution high rosolution gas chromatography-high resolation mass spectrometry in ambient air samples.Chinese journal of analytical chemistry,36(2),150-156. |
| MLA | Li Hui-Ru,et al."Establishment and application of the analysis method of pbdd/fs and pcdd/fs with isotope dilution high rosolution gas chromatography-high resolation mass spectrometry in ambient air samples".Chinese journal of analytical chemistry 36.2(2008):150-156. |
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来源：中国科学院大学
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