Electrochemical and photochemical characterization of novel ferrocenyl-azobenzene labeled pna monomers for dna detection
文献类型：期刊论文
| 作者 | Li, Jindu1,2; Chen, Miao1; Zhang, Haobo1,2; Liu, Sheng1,2 |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 11期号:4页码:392-395 |
| 关键词 | Peptide nucleic acid (pna) Ferrocene Azobenzene Electrochemistry Photochemistry |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2007.10.021 |
| 通讯作者 | Chen, miao(miaochen@lzb.ac.cn) |
| 英文摘要 | Ferrocenyl-azobenzene carboxylic acid was synthesized and used as electrochemically and spectroscopically active marker that was conjugated to thymine pna monomer. ferrocenyl-azobenzene labeled pna monomer of thymine (fc-azo-t) shows highly electrochemical and photochemical activity. the detection limit of fc-azo-t can reach 10(-6) m by using differential pulsed voltammogram (dpv), and the uv-vis limit is in the order 10(-7) m in ethanol. fc-azo-t can undergo facile isomerization by photoirradiation. the results give great motivity for synthesizing ferrocenyl-azobenzene labeled pna oligomers used as an effective electrochemical and photochemical probes. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | PEPTIDE NUCLEIC-ACID ; THYMINE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000255466600010 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2393063 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Miao |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jindu,Chen, Miao,Zhang, Haobo,et al. Electrochemical and photochemical characterization of novel ferrocenyl-azobenzene labeled pna monomers for dna detection[J]. Inorganic chemistry communications,2008,11(4):392-395. |
| APA | Li, Jindu,Chen, Miao,Zhang, Haobo,&Liu, Sheng.(2008).Electrochemical and photochemical characterization of novel ferrocenyl-azobenzene labeled pna monomers for dna detection.Inorganic chemistry communications,11(4),392-395. |
| MLA | Li, Jindu,et al."Electrochemical and photochemical characterization of novel ferrocenyl-azobenzene labeled pna monomers for dna detection".Inorganic chemistry communications 11.4(2008):392-395. |
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来源：中国科学院大学
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