An effective hg(2+)-selective fluorescent chemosensor based on a calix[4]arene bearing four dansyl amides
文献类型：期刊论文
| 作者 | Li Guang-Ke1,2; Liu Min1,2; Yang Guo-Qiang1; Chen Chuan-Feng1; Huang Zhi-Tang1 |
| 刊名 | Chinese journal of chemistry
 |
| 出版日期 | 2008-08-01 |
| 卷号 | 26期号:8页码:1440-1446 |
| 关键词 | Hg(2+) recognition Fluorescent chemosensor Calix[4]arene Dansyl amide |
| ISSN号 | 1001-604X |
| 通讯作者 | Chen chuan-feng(cchen@iccas.ac.cn) |
| 英文摘要 | A new calix[4]arene-based fluorescent chemosensor bearing- four dansyl amides on the upper rim (1) was conveniently synthesized. which showed hi-h sensitivity and selectivity toward hg(2+) over a wide range of metal ions in 50% aqueous acetonitrile. the complexation of hg(2+) ion induced a strong fluorescence quenching of 1 due to a well-defined electron transfer process from the dansyl group(s) to the metal center. compared with compounds 2 and 3. tetradansyl amide substituted calix[4]arene 1 showed a preorganized and coordinated complexing site for metal ions. moreover, the detection limit for hg(2+) was found to be 3.41 x 10(-6) mol center dot l(-1), which might make 1 a potentially practical hg(2+)-selective fluorescent sensor in aqueous system. |
| WOS关键词 | TRANSITION-METAL IONS ; HG2+ IONS ; LUMINESCENT CHEMOSENSORS ; AQUEOUS-SOLUTION ; UPPER-RIM ; SENSOR ; RECOGNITION ; SELECTIVITY ; MERCURY(II) ; BINDING |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000258940100016 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2393166 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen Chuan-Feng |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Guang-Ke,Liu Min,Yang Guo-Qiang,et al. An effective hg(2+)-selective fluorescent chemosensor based on a calix[4]arene bearing four dansyl amides[J]. Chinese journal of chemistry,2008,26(8):1440-1446. |
| APA | Li Guang-Ke,Liu Min,Yang Guo-Qiang,Chen Chuan-Feng,&Huang Zhi-Tang.(2008).An effective hg(2+)-selective fluorescent chemosensor based on a calix[4]arene bearing four dansyl amides.Chinese journal of chemistry,26(8),1440-1446. |
| MLA | Li Guang-Ke,et al."An effective hg(2+)-selective fluorescent chemosensor based on a calix[4]arene bearing four dansyl amides".Chinese journal of chemistry 26.8(2008):1440-1446. |
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来源：中国科学院大学
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