Study on cu-mn-si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process
文献类型：期刊论文
| 作者 | Zheng, Hong-Yan1,2; Zhu, Yu-Lei1; Huang, Long1,2; Zeng, Zhi-Yong1,2; Wan, Hai-Jun1,2; Li, Yong-Wang1 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2008-03-01 |
| 卷号 | 9期号:3页码:342-348 |
| 关键词 | Manganese Cu-mn-si catalyst Cyclohexanone 2-methylfuran Coupling process Cyclohexanol dehydrogenation Furfural hydrogenation |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2007.06.026 |
| 通讯作者 | Zhu, yu-lei(zhuyulei3025@yahoo.com) |
| 英文摘要 | A series of cu-mn-si catalysts for synthesis of cyclohexanone (chn) and 2-methylfuran (2-mf) through the coupling of cyclohexanol (chl) dehydrogenation and furfural (ffa) hydrogenation were prepared by co-precipitation method. the catalysts were characterized by using n, physisorption, x-ray diffraction (xrd), h-2 temperature programmed reduction (h,-tpr), n2o-chemisorption and ammonia temperature-programmed desorption (nh3-tpd) methods. the results show that metal-silica/or metal-metal interactions are presented in the catalysts, and the contents of copper, manganese and silicon affect the bet surface area, acidity and copper dispersion. the results of the catalytic tests indicate that manganese increases the activity of chl dehydrogenation and ffa hydrogenation as well as the selectivity of 2-mf. a cu-mn-si catalyst including appropriate copper, manganese and silicon is found to be most active, selective and stable under reaction conditions. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | VAPOR-PHASE HYDROGENATION ; COPPER-CONTAINING CATALYSTS ; GAS SHIFT REACTION ; GAMMA-BUTYROLACTONE ; CU/SIO2 CATALYSTS ; FURFURYL ALCOHOL ; OXIDATION-STATE ; REFORMED FUELS ; DME SYNTHESIS ; MIXED OXIDES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000252293400005 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2393382 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhu, Yu-Lei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers SKLCC, Taiyuan 030001, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 10039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Hong-Yan,Zhu, Yu-Lei,Huang, Long,et al. Study on cu-mn-si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process[J]. Catalysis communications,2008,9(3):342-348. |
| APA | Zheng, Hong-Yan,Zhu, Yu-Lei,Huang, Long,Zeng, Zhi-Yong,Wan, Hai-Jun,&Li, Yong-Wang.(2008).Study on cu-mn-si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process.Catalysis communications,9(3),342-348. |
| MLA | Zheng, Hong-Yan,et al."Study on cu-mn-si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process".Catalysis communications 9.3(2008):342-348. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。