Synthesis, characterization and solution properties of hydrophobically modified polyelectrolyte poly(aa-co-tmspma)
文献类型：期刊论文
| 作者 | Zhang, Huaiping1,2,3; Xu, Kai1; Ai, Hao1; Chen, Dehong1; Xv, Linli1; Chen, Mingcai1 |
| 刊名 | Journal of solution chemistry
 |
| 出版日期 | 2008-08-01 |
| 卷号 | 37期号:8页码:1137-1148 |
| 关键词 | Hydrophobically modified polyelectrolyte Supercritical carbon dioxide Ph-sensitive Associating morphologies Critical micelle concentration |
| ISSN号 | 0095-9782 |
| DOI | 10.1007/s10953-008-9300-4 |
| 通讯作者 | Zhang, huaiping(huaipingzhang@gmail.com) |
| 英文摘要 | The hydrophobically modified polyelectrolyte was synthesized using precipitation polymerization of acrylic acid and 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate (tmspma) in various molar ratios in supercritical carbon dioxide. ft-ir, (1)h nmr, capillary viscometry, rotational viscometer, transmission electron microscopy and fluorescence spectroscopy were used to characterize this copolymer. the viscosity of the copolymers showed a strong dependence on ph with a maximum at ph=5.5. associating morphologies of the copolymer were observed by tem. associating morphologies of poly(aa-co-tmspma) solution changed from a global structure to a shell-core structure with increasing hydrophobic levels. a solution of sample pat4 with a shell-core structure had the largest viscosity value. in addition, the critical micelle concentration of copolymer solution, cmc, was determined from the relative viscosity. the critical micelle concentration was further confirmed by fluorescence spectroscopy using 1-pyrenemethylamine hydrochloride, pymea center dot hcl, as a cationic fluorescent probe. the cmc was determined from the intensity ratios, the first to the third emission peaks i (1)/i (3), and the excimer to monomer i (e)/i (m) ratio of the pyrene probe as a function of concentration. |
| WOS关键词 | SUPERCRITICAL CARBON-DIOXIDE ; MODIFIED POLY(ACRYLIC ACID) ; ACRYLIC-ACID ; PRECIPITATION POLYMERIZATION ; BLOCK-COPOLYMERS ; FLUORESCENCE ; BEHAVIOR ; ACRYLAMIDE ; MICELLES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000257464100008 |
| 出版者 | SPRINGER/PLENUM PUBLISHERS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2393483 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhang, Huaiping |
| 作者单位 | 1.Chinese Acad Sci, GuangZhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China 2.Tai Yuan Univ Technol, Taiyuan 030024, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Huaiping,Xu, Kai,Ai, Hao,et al. Synthesis, characterization and solution properties of hydrophobically modified polyelectrolyte poly(aa-co-tmspma)[J]. Journal of solution chemistry,2008,37(8):1137-1148. |
| APA | Zhang, Huaiping,Xu, Kai,Ai, Hao,Chen, Dehong,Xv, Linli,&Chen, Mingcai.(2008).Synthesis, characterization and solution properties of hydrophobically modified polyelectrolyte poly(aa-co-tmspma).Journal of solution chemistry,37(8),1137-1148. |
| MLA | Zhang, Huaiping,et al."Synthesis, characterization and solution properties of hydrophobically modified polyelectrolyte poly(aa-co-tmspma)".Journal of solution chemistry 37.8(2008):1137-1148. |
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来源：中国科学院大学
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