A new triphenylamine-based hyperbranched polyfluorene with oxadiazole units on its side chains
文献类型：期刊论文
| 作者 | Wu, Guanglong1,2; Yang, Yi1,2; He, Chang1,2; Chen, Xiaomin1; Li, Yongfang1 |
| 刊名 | European polymer journal
 |
| 出版日期 | 2008-12-01 |
| 卷号 | 44期号:12页码:4047-4053 |
| 关键词 | Hyperbranched polymer Suzuki polycondensation Triphenylamine Oxadiazole |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2008.09.018 |
| 通讯作者 | Li, yongfang(liyf@iccas.ac.cn) |
| 英文摘要 | A new triphenylamine-based hyperbranched polymer with electron deficient units of oxadiazole on its side chains was successfully prepared by a modified suzuki polycondensation with pd(pph(3))(4) as a catalyst, k(2)co(3) as a base, and a mixture of thf/toluene (1:1) as the solvent, the electron deficient units of oxadiazole were used to improve the electron injection and transport of the polymer. the results of the cyclic voltammetry (cv) of the polymer indicate that the homo and lumo energy levels match well with the work function of the ito/pedot anode and the metal cathode, respectively. moreover, the hyperbranched polymer shows blue-emission and the hyperbranched structure effectively suppressed the formation of the aggregates/excimers in the polymer film. (c) 2008 elsevier ltd. all rights reserved. |
| WOS关键词 | CONJUGATED POLYMERS ; ELECTROLUMINESCENT PROPERTIES ; 2-PHOTON ABSORPTION ; GREEN EMISSION ; COPOLYMERS ; PHOTOLUMINESCENCE ; STABILITY ; FLUORENE ; ORIGIN |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000262068400017 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2393577 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Yongfang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Guanglong,Yang, Yi,He, Chang,et al. A new triphenylamine-based hyperbranched polyfluorene with oxadiazole units on its side chains[J]. European polymer journal,2008,44(12):4047-4053. |
| APA | Wu, Guanglong,Yang, Yi,He, Chang,Chen, Xiaomin,&Li, Yongfang.(2008).A new triphenylamine-based hyperbranched polyfluorene with oxadiazole units on its side chains.European polymer journal,44(12),4047-4053. |
| MLA | Wu, Guanglong,et al."A new triphenylamine-based hyperbranched polyfluorene with oxadiazole units on its side chains".European polymer journal 44.12(2008):4047-4053. |
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来源：中国科学院大学
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