The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
文献类型：期刊论文
| 作者 | Tang, Cong-Ming1,2,3,4; Zeng, Yi1; Yang, Xian-Gui1; Lei, Yong-Cheng1; Wang, Gong-Ying1,3 |
| 刊名 | Journal of molecular catalysis a-chemical
 |
| 出版日期 | 2009-12-01 |
| 卷号 | 314期号:1-2页码:15-20 |
| 关键词 | Acrylic acid Palladium acetate Diphenyl-2-pyridylphosphine Trifluoromethane sulfonic acid Hydrocarboxylation Acetylene Carbon monoxide |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2009.08.008 |
| 通讯作者 | Wang, gong-ying() |
| 英文摘要 | Hydrocarboxylation of acetylene with carbon monoxide to acrylic acid has been carried out using a catalyst system consisting of pd(oac)(2). phosphine ligands and acids under the mild conditions. the effects of acidic promoters, phosphine ligands, water. reaction time and the initial partial pressure of carbon monoxide oil the conversion of acetylene as well as the selectivity to acrylic acid have been investigated among all ligands as used, only diphenyl-2-pyridylphosphine has a good catalytic activity. sulfonic acids and trifluoroacetic acid as acidic promoters display an excellent performance. effects of water and the initial partial pressure of carbon monoxide have also been discussed. under the optimal reaction conditions, 85% conversion of acetylene and 99% selectivity to acrylic acid as well as 1011 h(-1) tof have been achieved. crown copyright (c) 2009 published by elsevier b v all rights reserved. |
| WOS关键词 | COMPLEX CATALYST ; REPPE CARBONYLATION ; HYDROESTERIFICATION ; ALKYNES ; PRESSURE ; CARBOXYLATION ; PHOSPHINES ; WATER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000272114300003 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2394018 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Gong-Ying |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.China W Normal Univ, Coll Chem & Chem Engn, Nanchong 637002, Sichuan, Peoples R China 3.Changzhou Inst Chem, Changzhou 213164, Jiangshu, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Cong-Ming,Zeng, Yi,Yang, Xian-Gui,et al. The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions[J]. Journal of molecular catalysis a-chemical,2009,314(1-2):15-20. |
| APA | Tang, Cong-Ming,Zeng, Yi,Yang, Xian-Gui,Lei, Yong-Cheng,&Wang, Gong-Ying.(2009).The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions.Journal of molecular catalysis a-chemical,314(1-2),15-20. |
| MLA | Tang, Cong-Ming,et al."The palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions".Journal of molecular catalysis a-chemical 314.1-2(2009):15-20. |
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来源：中国科学院大学
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