Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(ii) electrochemiluminescence
文献类型：期刊论文
| 作者 | Li, Haijuan1,2; Shi, Lihong1,2; Liu, Xiaoqing1,2; Niu, Wenxin1,2; Xu, Guobao1 |
| 刊名 | Electrophoresis
 |
| 出版日期 | 2009-11-01 |
| 卷号 | 30期号:22页码:3926-3931 |
| 关键词 | Capillary electrophoresis Electrochemiluminescence Electrochemistry Isocyanates Ruthenium |
| ISSN号 | 0173-0835 |
| DOI | 10.1002/elps.200900281 |
| 通讯作者 | Xu, guobao(guobaoxu@ciac.jl.cn) |
| 英文摘要 | Ce with tris(2,2'-bipyridyl) ruthenium(ii) (ru(bpy)(3)(2+)) electrochemiluminescence (ecl) detection for the quantitative determination of isocyanates was first reported. hexamethylene diisocyanate (hdi) and hexyl isocyanate (hi) were used as the model analytes. commercially available n,n-diethyl-n'-methylethylenediamine was used as the derivatization reagent. it has both a secondary amine group and a tertiary amine group. the secondary amine group can quantitatively react with isocyanate group, and the tertiary amine group can react with ru(bpy)(3)(2+) to produce strong ecl signal for sensitive detection. the derivatization reaction was almost instantaneous and is much faster than other reported derivative reactions using other derivative reagents. the urea formed was stable. linear calibration curve was obtained in the range from 0.01 to 10 mu m for hdi, and 0.02 to 20 mu m for hexyl isocyanate (hi). the detection limit is 0.01 mu m for hdi and 0.02 mu m for hi. the method is more sensitive than uv-detection and electrochemical detection. for practical application, recovery higher than 90% for hdi and hi was |
| WOS关键词 | SOLID-STATE ELECTROCHEMILUMINESCENCE ; ELECTROGENERATED CHEMI-LUMINESCENCE ; PERFORMANCE LIQUID-CHROMATOGRAPHY ; COMPOSITE FILMS ; TERTIARY-AMINES ; HEXAMETHYLENE DIISOCYANATE ; AIRBORNE ISOCYANATES ; ZONE-ELECTROPHORESIS ; AQUEOUS-SOLUTION ; ULTRATHIN FILMS |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS类目 | Biochemical Research Methods ; Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000272474900017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2394291 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Guobao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Haijuan,Shi, Lihong,Liu, Xiaoqing,et al. Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(ii) electrochemiluminescence[J]. Electrophoresis,2009,30(22):3926-3931. |
| APA | Li, Haijuan,Shi, Lihong,Liu, Xiaoqing,Niu, Wenxin,&Xu, Guobao.(2009).Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(ii) electrochemiluminescence.Electrophoresis,30(22),3926-3931. |
| MLA | Li, Haijuan,et al."Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(ii) electrochemiluminescence".Electrophoresis 30.22(2009):3926-3931. |
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来源：中国科学院大学
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