The nickel and copper-catalyzed hydroformylation of acetylene with carbon monoxide to acrylic acid
文献类型：期刊论文
| 作者 | Tang, Congming1,2,3,4; Zeng, Yi2; Cao, Ping2,3,4; Yang, Xiangui2; Wang, Gongying1,2 |
| 刊名 | Catalysis letters
 |
| 出版日期 | 2009-04-01 |
| 卷号 | 129期号:1-2页码:189-193 |
| 关键词 | Non-petroleum synthesis Acrylic acid Nickel acetate tetrahydrate Cupric bromid Triphenylphosphine Methanesulfonic acid |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-008-9789-6 |
| 通讯作者 | Wang, gongying(gywang@cioc.ac.cn) |
| 英文摘要 | A non-petroleum approach for the catalytic synthesis of acrylic acid by hydroformylation of acetylene with carbon monoxide has been studied under various conditions. mixtures of nickel acetate tetrahydrate, cupric bromid, triphenylphosphine and methanesulfonic acid are used as catalysts, and tetrahydrofuran as solvent. the effect of cupric bromid, triphenylphosphine and methanesulfonic acid and water on the conversion of acetylene as well as the selectivity to acrylic acid has been studied. triphenylphosphine is found to be effient for enhancement of the selectivity under the experimental conditions. when the reaction was carried out under the total initial pressure of 6.0 mpa at the temperature of 200 a degrees c with the catalyst composition of 2.0 mmol ni(oac)(2) 4h(2)o, 0.9 mmol cubr(2), 2.0 mmol ch(3)so(3)h and 4.0 mmol pph(3), 90% conversion of acetylene and 90% selectivity to acrylic acid were achieved. |
| WOS关键词 | REPPE CARBONYLATION ; COMPLEX CATALYST ; HYDROESTERIFICATION ; PRESSURE ; ALKYNES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000264318300027 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2394536 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Gongying |
| 作者单位 | 1.China W Normal Univ, Coll Chem & Chem Engn, Nanchong 637002, Sichuan, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 3.Changzhou Inst Chem, Changzhou 213164, Jaingshu, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Congming,Zeng, Yi,Cao, Ping,et al. The nickel and copper-catalyzed hydroformylation of acetylene with carbon monoxide to acrylic acid[J]. Catalysis letters,2009,129(1-2):189-193. |
| APA | Tang, Congming,Zeng, Yi,Cao, Ping,Yang, Xiangui,&Wang, Gongying.(2009).The nickel and copper-catalyzed hydroformylation of acetylene with carbon monoxide to acrylic acid.Catalysis letters,129(1-2),189-193. |
| MLA | Tang, Congming,et al."The nickel and copper-catalyzed hydroformylation of acetylene with carbon monoxide to acrylic acid".Catalysis letters 129.1-2(2009):189-193. |
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来源：中国科学院大学
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