Fluorescent alteration on a bistable molecular shuttle
文献类型：期刊论文
| 作者 | Zhou, Weidong1,2; Zhang, Shuai3; Li, Guoxing1,2; Zhao, Yingjie1,2; Shi, Zhiqiang3; Liu, Huibiao1,2; Li, Yuliang1,2 |
| 刊名 | Chemphyschem
 |
| 出版日期 | 2009-08-24 |
| 卷号 | 10期号:12页码:2066-2072 |
| 关键词 | Electron transfer Fluorescence Macrocycles Molecular motors Rotaxane |
| ISSN号 | 1439-4235 |
| DOI | 10.1002/cphc.200900228 |
| 通讯作者 | Li, yuliang(ylli@iccas.ac.cn) |
| 英文摘要 | Solvent driven molecular shuttles containing a pyrene-connected macrocycle and an intramolecular charge-transfer (ict) chromophore stopper are constructed. in one of the molecular shuttles, a long c-10 chain is introduced in the thread to separate the peptide station and the ict stopper. the macrocycle stays in the peptide station in apolar solvents and moves to the c10-chain station in highly polar solvents. this moving process alters the electronic interaction between the pyrene unit in the macrocycle and the ict stopper, which induces the change of the pyrene fluorescence emission. the molecular shuttle exhibits stronger emission when the macrocycle is adjacent to the ict stopper. |
| WOS关键词 | LINEAR ROTAXANE DIMER ; TRANSLATIONAL MOTION ; 2+2 CYCLOADDITION ; ENERGY-TRANSFER ; DRIVEN ; SWITCH ; MACROCYCLE ; MACHINE ; POLYMER ; CHROMOPHORES |
| WOS研究方向 | Chemistry ; Physics |
| WOS类目 | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000269398800017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2394593 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Yuliang |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China 3.Shandong Normal Univ, Dept Chem, Jianan 250014, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Weidong,Zhang, Shuai,Li, Guoxing,et al. Fluorescent alteration on a bistable molecular shuttle[J]. Chemphyschem,2009,10(12):2066-2072. |
| APA | Zhou, Weidong.,Zhang, Shuai.,Li, Guoxing.,Zhao, Yingjie.,Shi, Zhiqiang.,...&Li, Yuliang.(2009).Fluorescent alteration on a bistable molecular shuttle.Chemphyschem,10(12),2066-2072. |
| MLA | Zhou, Weidong,et al."Fluorescent alteration on a bistable molecular shuttle".Chemphyschem 10.12(2009):2066-2072. |
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来源：中国科学院大学
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