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Chinese Academy of Sciences Institutional Repositories Grid
Effects of polymeric curing agent modified with silazanes on the mechanical properties of silicone rubber

文献类型:期刊论文

作者Dai, Lina1,2; Zhang, Zhijie1; Zhao, Yunfeng1; Liu, Hongming1; Xie, Zemin1
刊名Journal of applied polymer science
出版日期2009-01-15
卷号111期号:2页码:1057-1062
关键词Mechanical properties Rubber Fillers Silazane Swelling
ISSN号0021-8995
DOI10.1002/app.29063
通讯作者Zhang, zhijie(zhangzj@iccas.ac.cn)
英文摘要Polymeric curing agent modified with hexamethyldisilazane (pca-d), or with hexamethylcyclotrisilazane (pca-t), was used to improve the mechanical properties of hydroxyl-teminated polydimethylsiloxane (pdms) rubber. the structure and the gel time of pca were characterized by (29)si nmr and shear viscosity measurement, respectively. the pca modified with silazanes was more stable in storage than that without treatment (pca-0). chemical bonds were formed during the reaction of silazanes and pca according to (29)si nmr results. the crosslink density (gamma(e)) and the mechanical properties of pca/pdms rubber were determined by swelling equilibrium and stress-strain tests. it was found that pca treated with both silazanes could better enhance the mechanical properties of pca/pdms rubber compared with pca-0. pca-t/pdms rubber, with additional crosslinks, was the best among the three types of pca/pdms rubber on the mechanical properties. (c) 2008 wiley periodicals, inc. j appl polym sci 111: 1057-1062, 2009
WOS关键词SOL-GEL PROCESS ; HEXAMETHYLDISILAZANE ; REINFORCEMENT ; HEXAMETHYLCYCLOTRISILAZANE ; ELASTOMERS ; MIXTURES ; SURFACE
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000261152500080
出版者JOHN WILEY & SONS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2395056
专题中国科学院大学
通讯作者Zhang, Zhijie
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Adv Polymer Mat, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Dai, Lina,Zhang, Zhijie,Zhao, Yunfeng,et al. Effects of polymeric curing agent modified with silazanes on the mechanical properties of silicone rubber[J]. Journal of applied polymer science,2009,111(2):1057-1062.
APA Dai, Lina,Zhang, Zhijie,Zhao, Yunfeng,Liu, Hongming,&Xie, Zemin.(2009).Effects of polymeric curing agent modified with silazanes on the mechanical properties of silicone rubber.Journal of applied polymer science,111(2),1057-1062.
MLA Dai, Lina,et al."Effects of polymeric curing agent modified with silazanes on the mechanical properties of silicone rubber".Journal of applied polymer science 111.2(2009):1057-1062.

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来源:中国科学院大学

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