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Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives

文献类型:期刊论文

作者Cao, Jing1,2; Lu, Hai-Yan2; Chen, Chuan-Feng1
刊名Tetrahedron
出版日期2009-09-26
卷号65期号:39页码:8104-8112
关键词Pentiptycene quinones Synthesis and structure Self-assembly in the solid state Photo-physical property Electrochemistry property
ISSN号0040-4020
DOI10.1016/j.tet.2009.07.090
通讯作者Chen, chuan-feng(cchen@iccas.ac.cn)
英文摘要A series of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives have been synthesized. especially, it was found that if two o-dimethoxybenzene moieties were situated at the same side of the pentiptycene quinones, one of them was only oxidized by excess can in aqueous acetonitrile. moreover, the pentiptycene quinones with unique 3d rigid structure could all self-assemble into a 3d microporous structure in the solid state. for the pentiptycene quinones containing the dimethoxybenzene unit(s) and the quinone group(s) simultaneously, interesting intramolecular charge transfer interactions and electrochemical properties were also shown. these peripheral-substituted pentiptycene quinones and their o-quinone derivatives can be used as new useful building blocks and will find wide applications in material science and host-guest chemistry. (c) 2009 elsevier ltd. all rights reserved.
WOS关键词CHARGE-TRANSFER INTERACTION ; PARAQUAT DERIVATIVES ; MACROTRICYCLIC HOST ; TRANSFER TRANSITION ; POLYMER-FILMS ; TRIPTYCENE ; COMPLEXATION ; TNT ; SALTS
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
WOS记录号WOS:000270121400004
出版者PERGAMON-ELSEVIER SCIENCE LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2396042
专题中国科学院大学
通讯作者Chen, Chuan-Feng
作者单位1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Cao, Jing,Lu, Hai-Yan,Chen, Chuan-Feng. Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives[J]. Tetrahedron,2009,65(39):8104-8112.
APA Cao, Jing,Lu, Hai-Yan,&Chen, Chuan-Feng.(2009).Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives.Tetrahedron,65(39),8104-8112.
MLA Cao, Jing,et al."Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives".Tetrahedron 65.39(2009):8104-8112.

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来源:中国科学院大学

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