Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives
文献类型:期刊论文
作者 | Cao, Jing1,2; Lu, Hai-Yan2; Chen, Chuan-Feng1 |
刊名 | Tetrahedron
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出版日期 | 2009-09-26 |
卷号 | 65期号:39页码:8104-8112 |
关键词 | Pentiptycene quinones Synthesis and structure Self-assembly in the solid state Photo-physical property Electrochemistry property |
ISSN号 | 0040-4020 |
DOI | 10.1016/j.tet.2009.07.090 |
通讯作者 | Chen, chuan-feng(cchen@iccas.ac.cn) |
英文摘要 | A series of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives have been synthesized. especially, it was found that if two o-dimethoxybenzene moieties were situated at the same side of the pentiptycene quinones, one of them was only oxidized by excess can in aqueous acetonitrile. moreover, the pentiptycene quinones with unique 3d rigid structure could all self-assemble into a 3d microporous structure in the solid state. for the pentiptycene quinones containing the dimethoxybenzene unit(s) and the quinone group(s) simultaneously, interesting intramolecular charge transfer interactions and electrochemical properties were also shown. these peripheral-substituted pentiptycene quinones and their o-quinone derivatives can be used as new useful building blocks and will find wide applications in material science and host-guest chemistry. (c) 2009 elsevier ltd. all rights reserved. |
WOS关键词 | CHARGE-TRANSFER INTERACTION ; PARAQUAT DERIVATIVES ; MACROTRICYCLIC HOST ; TRANSFER TRANSITION ; POLYMER-FILMS ; TRIPTYCENE ; COMPLEXATION ; TNT ; SALTS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000270121400004 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2396042 |
专题 | 中国科学院大学 |
通讯作者 | Chen, Chuan-Feng |
作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Cao, Jing,Lu, Hai-Yan,Chen, Chuan-Feng. Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives[J]. Tetrahedron,2009,65(39):8104-8112. |
APA | Cao, Jing,Lu, Hai-Yan,&Chen, Chuan-Feng.(2009).Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives.Tetrahedron,65(39),8104-8112. |
MLA | Cao, Jing,et al."Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives".Tetrahedron 65.39(2009):8104-8112. |
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来源:中国科学院大学
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