Novel biodegradable amphiphilic poly(epsilon-caprolactone)/poly(n-vinylpyrrolidone) blends via successive in situ polymerizations
文献类型：期刊论文
| 作者 | Xing, Zhimin1,2; Xie, Tingxiu; Yang, Guisheng1,3 |
| 刊名 | Journal of applied polymer science
 |
| 出版日期 | 2009-02-15 |
| 卷号 | 111期号:4页码:1676-1683 |
| 关键词 | Amphiphilic Poly(epsilon-caprolactone) Poly(n-vinylpyrrolidone) Blends Ring-openingpolymerization |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.29176 |
| 通讯作者 | Yang, guisheng(ygs@geniuscn.com) |
| 英文摘要 | In this study, biodegradable blends of poly(epsilon-carprolactone) (pcl) and poly(n-vinylpyrrolidone) (pvp) were prepared by a new strategy in the following steps: (1) free radical polymerization of n-vinyl-2-pyrrolidone (nvp) in epsilon-caprolactone (cl); (2) ring-opening polymerization of epsilon-caprolactone in the presence of pvp to obtain the target blends. the structure of the blends was confirmed by ftir and h-l nmr, and the molecular weight of pcl and pvp were determined by gps. sem study revealed that this polymerization method could decrease the disperse phase size and improve the interphase when compared with solution-blending method. the phase inversion occurred when pvp content was 15-20 wt %. subsequently, the pcl sphere dispersed in pvp matrix and its size decreased with the increase of pvp content. the contact angle results showed that pcl/pvp blend. pcl/pvp blends are believed to be promising for drug delivery, cell therapy, and other biomedical applications. (c) 2008 wiley periodicals, inc. j appl polym sci 111: 1676-1683, 2009 |
| WOS关键词 | PHOSPHATE BUFFER SOLUTION ; ALIPHATIC POLYESTERS ; ENZYMATIC DEGRADATION ; MECHANICAL-PROPERTIES ; EPSILON-CAPROLACTONE ; ALPHA-CYCLODEXTRIN ; COPOLYMERS ; POLYCAPROLACTONE ; POLYSACCHARIDES ; NANOPARTICLES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000261896900023 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2396097 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Technol, Beijing Natl Lab Mol Sci,Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing, Zhimin,Xie, Tingxiu,Yang, Guisheng. Novel biodegradable amphiphilic poly(epsilon-caprolactone)/poly(n-vinylpyrrolidone) blends via successive in situ polymerizations[J]. Journal of applied polymer science,2009,111(4):1676-1683. |
| APA | Xing, Zhimin,Xie, Tingxiu,&Yang, Guisheng.(2009).Novel biodegradable amphiphilic poly(epsilon-caprolactone)/poly(n-vinylpyrrolidone) blends via successive in situ polymerizations.Journal of applied polymer science,111(4),1676-1683. |
| MLA | Xing, Zhimin,et al."Novel biodegradable amphiphilic poly(epsilon-caprolactone)/poly(n-vinylpyrrolidone) blends via successive in situ polymerizations".Journal of applied polymer science 111.4(2009):1676-1683. |
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来源：中国科学院大学
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