中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Control of large-scale wettability using micro-amounts of selective solvents

文献类型:期刊论文

作者Zhao Tian-Yi1,2; Zhang Yong1; Liu Huan1; Wang Shu-Tao1; Zhang Zhi-Jie1; Jiang Lei1
刊名Chemical journal of chinese universities-chinese
出版日期2009-11-10
卷号30期号:11页码:2301-2305
关键词Block copolymer Polymer film Micro-amount selective solvent Control of wettability
ISSN号0251-0790
通讯作者Zhang zhi-jie(zhangzj@iccas.ac.cn)
英文摘要A simple approach was used to control the large-scale wettability of polymer-coated surfaces merely by adding micro-amounts of selective solvents of different polarity to tri-block copolymer solutions. an amphiphilic tri-block copolymer, poly (ethylene oxide) -poly (dimethylsiloxane) -poly (ethylene oxide) (peo-pdms-peo), was used to form micelles and reverse micelles by adding micro-amounts of a selective solvent to the initial solution. the micellar and reverse micellar film coatings show different wettability from hydrophilic to hydrophobic, and even from superhydrophilic to superhydrophobic when micro-scale roughness is involved. the structures of the micelles and reverse micelles were studied by transmission electron microscopy and atomic force microscopy, and the surface chemical composition of the film coatings was determined by x-ray photoelectron spectroscopy (xps). the results reveal that the main cause of differences in wettability is the different surface chemical compositions induced by the different structures of micelles and reverse micelles.
WOS关键词BLOCK-COPOLYMERS ; SURFACES ; WATER ; TRANSITION ; MICELLES ; MORPHOLOGIES ; SEPARATION ; TEMPLATES ; FILMS
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000272832200039
出版者HIGHER EDUCATION PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2396099
专题中国科学院大学
通讯作者Zhang Zhi-Jie
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhao Tian-Yi,Zhang Yong,Liu Huan,et al. Control of large-scale wettability using micro-amounts of selective solvents[J]. Chemical journal of chinese universities-chinese,2009,30(11):2301-2305.
APA Zhao Tian-Yi,Zhang Yong,Liu Huan,Wang Shu-Tao,Zhang Zhi-Jie,&Jiang Lei.(2009).Control of large-scale wettability using micro-amounts of selective solvents.Chemical journal of chinese universities-chinese,30(11),2301-2305.
MLA Zhao Tian-Yi,et al."Control of large-scale wettability using micro-amounts of selective solvents".Chemical journal of chinese universities-chinese 30.11(2009):2301-2305.

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来源:中国科学院大学

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