Control of large-scale wettability using micro-amounts of selective solvents
文献类型:期刊论文
作者 | Zhao Tian-Yi1,2; Zhang Yong1; Liu Huan1; Wang Shu-Tao1; Zhang Zhi-Jie1; Jiang Lei1 |
刊名 | Chemical journal of chinese universities-chinese
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出版日期 | 2009-11-10 |
卷号 | 30期号:11页码:2301-2305 |
关键词 | Block copolymer Polymer film Micro-amount selective solvent Control of wettability |
ISSN号 | 0251-0790 |
通讯作者 | Zhang zhi-jie(zhangzj@iccas.ac.cn) |
英文摘要 | A simple approach was used to control the large-scale wettability of polymer-coated surfaces merely by adding micro-amounts of selective solvents of different polarity to tri-block copolymer solutions. an amphiphilic tri-block copolymer, poly (ethylene oxide) -poly (dimethylsiloxane) -poly (ethylene oxide) (peo-pdms-peo), was used to form micelles and reverse micelles by adding micro-amounts of a selective solvent to the initial solution. the micellar and reverse micellar film coatings show different wettability from hydrophilic to hydrophobic, and even from superhydrophilic to superhydrophobic when micro-scale roughness is involved. the structures of the micelles and reverse micelles were studied by transmission electron microscopy and atomic force microscopy, and the surface chemical composition of the film coatings was determined by x-ray photoelectron spectroscopy (xps). the results reveal that the main cause of differences in wettability is the different surface chemical compositions induced by the different structures of micelles and reverse micelles. |
WOS关键词 | BLOCK-COPOLYMERS ; SURFACES ; WATER ; TRANSITION ; MICELLES ; MORPHOLOGIES ; SEPARATION ; TEMPLATES ; FILMS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000272832200039 |
出版者 | HIGHER EDUCATION PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2396099 |
专题 | 中国科学院大学 |
通讯作者 | Zhang Zhi-Jie |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao Tian-Yi,Zhang Yong,Liu Huan,et al. Control of large-scale wettability using micro-amounts of selective solvents[J]. Chemical journal of chinese universities-chinese,2009,30(11):2301-2305. |
APA | Zhao Tian-Yi,Zhang Yong,Liu Huan,Wang Shu-Tao,Zhang Zhi-Jie,&Jiang Lei.(2009).Control of large-scale wettability using micro-amounts of selective solvents.Chemical journal of chinese universities-chinese,30(11),2301-2305. |
MLA | Zhao Tian-Yi,et al."Control of large-scale wettability using micro-amounts of selective solvents".Chemical journal of chinese universities-chinese 30.11(2009):2301-2305. |
入库方式: iSwitch采集
来源:中国科学院大学
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