A novel moisture-resistant film for niso4 center dot 6h(2)o filter based on isophorone diisocyanate-bridged polysilsesquioxane
文献类型：期刊论文
| 作者 | Hu, Shengwei1,2; Yang, Dongjiang3; Xu, Yao1; Wu, Dong1; Sun, Yuhan1 |
| 刊名 | Materials chemistry and physics
 |
| 出版日期 | 2009-04-15 |
| 卷号 | 114期号:2-3页码:868-873 |
| 关键词 | Moisture-resistant Film Uv light filter Polysilsesquioxane |
| ISSN号 | 0254-0584 |
| DOI | 10.1016/j.matchemphys.2008.10.071 |
| 通讯作者 | Xu, yao(xuyao@sxicc.ac.cn) |
| 英文摘要 | A new bridged silsesquioxane (bsq) was synthesized with isophorone diisocyanate (ipdi) and 3-aminopropyltriethoxysilane (aptes). highly cross-linked bridged polysilsesquioxane (bpsq) sol was prepared by the sol-gel polycondensation of the as-synthesized bsq under basic catalysis. transparent film was obtained by dip-coating the bpsq sol on the nickel sulfate hexhydrate (nsh, niso4 center dot 6h(2)o) crystal wafer, an important kind of uv light filter used at wavelength 300 nm. the obtained bpsq film was nonporous (pore volume is 2 x 10(-3) cm(3) g(-1)) and exhibited very high condensation degree of siloxane (99.0%). this film showed high optical transmittance and excellent moisture-resistant protection to the nsh filter. moreover, the thermal stability of the nsh filter was also greatly improved by the as-prepared bpsq film. (c) 2008 elsevier b.v. all rights reserved |
| WOS关键词 | ORGANIC-INORGANIC MATERIALS ; NICKEL SULFATE HEXAHYDRATE ; GROWTH ; POLYURETHANES ; MONODISPERSE ; PRECURSORS ; NETWORKS ; POLYMERS ; COATINGS ; CRYSTAL |
| WOS研究方向 | Materials Science |
| WOS类目 | Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000263833500065 |
| 出版者 | ELSEVIER SCIENCE SA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2396427 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Yao |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Queensland Univ Technol, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia |
| 推荐引用方式 GB/T 7714 | Hu, Shengwei,Yang, Dongjiang,Xu, Yao,et al. A novel moisture-resistant film for niso4 center dot 6h(2)o filter based on isophorone diisocyanate-bridged polysilsesquioxane[J]. Materials chemistry and physics,2009,114(2-3):868-873. |
| APA | Hu, Shengwei,Yang, Dongjiang,Xu, Yao,Wu, Dong,&Sun, Yuhan.(2009).A novel moisture-resistant film for niso4 center dot 6h(2)o filter based on isophorone diisocyanate-bridged polysilsesquioxane.Materials chemistry and physics,114(2-3),868-873. |
| MLA | Hu, Shengwei,et al."A novel moisture-resistant film for niso4 center dot 6h(2)o filter based on isophorone diisocyanate-bridged polysilsesquioxane".Materials chemistry and physics 114.2-3(2009):868-873. |
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来源：中国科学院大学
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