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Improved compatibility of evoh/ldpe blends by gamma-ray irradiation

文献类型:期刊论文

作者Li, Haihong1,3; Yin, Yuan1,3; Liu, Meihua1; Deng, Pengyang1,2; Zhang, Wanxi3,4; Sun, Jiazhen1
刊名Advances in polymer technology
出版日期2009-09-01
卷号28期号:3页码:192-198
关键词Irradiation Mechanical properties Miscibility Polyethylene Polyvinyl alcohol
ISSN号0730-6679
DOI10.1002/adv.20160
通讯作者Deng, pengyang(dpyang@ciac.jl.cn)
英文摘要The change of compatibility of poly(ethylene-co-vinyl alcohol) (evoh)/ldpe blends induced by gamma-ray radiation was studied. gel extraction experiment results show that the gel fraction of blends increases linearly with the content of ldpe and reaches a maximum at 100 kgy, because neat evoh is difficult to cross-link by irradiation. a comparison of theoretical and experimental gel contents indicates that some evoh molecular chains enter the ldpe gel network. the peak at 3363 cm(-1) on the fourier transform infrared spectrum of pure blend gel is assigned to typical stretching of an -oh bond, which indicates that a "graft" reaction occurs in the interface between evoh and ldpe phases during the irradiation process. mechanical property measurement results support such a structural change. the tensile strength of cross-linked blends increases with absorbed dose first, reaches a maximum value at 150 kgy, and then decreases with dose. a similar trend can also be observed in bending tests. (c) 2009 wiley periodicals, inc. adv polym techn 28: 192-198, 2009; published online in wiley interscience (www.interscience.wiley.com). doi 10.1002/adv.20160
WOS关键词VINYL ALCOHOL COPOLYMER ; BARRIER PROPERTIES ; LDPE/EVOH BLENDS ; MECHANICAL-PROPERTIES ; MORPHOLOGY ; EVOH ; IONOMER ; BEHAVIOR ; FILMS
WOS研究方向Engineering ; Polymer Science
WOS类目Engineering, Chemical ; Polymer Science
语种英语
WOS记录号WOS:000272914700005
出版者JOHN WILEY & SONS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2397883
专题中国科学院大学
通讯作者Deng, Pengyang
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Jilin Univ, Dept Mat Sci & Engn, Changchun 130025, Jilin, Peoples R China
4.Dalian Univ Technol, Dept Mat Sci & Engn, Dalian 116024, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Li, Haihong,Yin, Yuan,Liu, Meihua,et al. Improved compatibility of evoh/ldpe blends by gamma-ray irradiation[J]. Advances in polymer technology,2009,28(3):192-198.
APA Li, Haihong,Yin, Yuan,Liu, Meihua,Deng, Pengyang,Zhang, Wanxi,&Sun, Jiazhen.(2009).Improved compatibility of evoh/ldpe blends by gamma-ray irradiation.Advances in polymer technology,28(3),192-198.
MLA Li, Haihong,et al."Improved compatibility of evoh/ldpe blends by gamma-ray irradiation".Advances in polymer technology 28.3(2009):192-198.

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来源:中国科学院大学

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