Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation
文献类型：期刊论文
| 作者 | Chen Li-Mei1,2; Liu Xia1; Jiang Sheng-Xiang1 |
| 刊名 | Chinese journal of analytical chemistry
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 37期号:2页码:255-258 |
| 关键词 | Cellulose tris(3, 5-dimethylphenylcarbamate) Chiral stationary phase Interactions Linear solvation energy relationship Support |
| ISSN号 | 0253-3820 |
| 通讯作者 | Liu xia(gsliuxia@lzb.ac.cn) |
| 英文摘要 | Linear solvation energy relationships (lser) were used to evaluate the interactions exited on cellulose tris (3, 5-dimethylphenylcarbamate) (cdmpc)-chiral stationary phase (csp) and the effect of the support on the chiral separation. the 33 solutes descriptors and their retention factors were used to the multiple linear regressions analysis and statistical calculations. and the interaction existed in the chiral stationary phases was evaluated by the system parameters obtained by the multiple linear regression analysis. there are weaker pi-pi interactions and stronger dipole- or induced dipole-type interactions on the chiral stationary phases in normal phase. and the h-bond existed in the chiral stationary phase is affected by the support. csp with aminopropy silica gel(aps) support has the stronger ability of h-bond donor, and csp with sio(2) support has the stronger ability of h-bond acceptor. |
| WOS关键词 | PERFORMANCE LIQUID-CHROMATOGRAPHY ; SOLVATION ENERGY RELATIONSHIPS ; SILICA-GEL ; RECOGNITION ; ENANTIOMERS ; RESOLUTION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000265169000018 |
| 出版者 | ELSEVIER SCIENCE INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2398565 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu Xia |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Li-Mei,Liu Xia,Jiang Sheng-Xiang. Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation[J]. Chinese journal of analytical chemistry,2009,37(2):255-258. |
| APA | Chen Li-Mei,Liu Xia,&Jiang Sheng-Xiang.(2009).Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation.Chinese journal of analytical chemistry,37(2),255-258. |
| MLA | Chen Li-Mei,et al."Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation".Chinese journal of analytical chemistry 37.2(2009):255-258. |
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来源：中国科学院大学
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