Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o
文献类型：期刊论文
| 作者 | Wang, Xin1,2; Sheng, Tian-Lu1; Chen, Jian-Shan1; Hu, Sheng-Min1; Fu, Rui-Biao1; Wu, Xin-Tao1 |
| 刊名 | Journal of molecular structure
 |
| 出版日期 | 2009-11-12 |
| 卷号 | 936期号:1-3页码:142-146 |
| 关键词 | Thioantimonate(iii) Crystal structure Thermoanalysis Semiconductor Impedance Bulk and grain conductivity |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2009.07.029 |
| 通讯作者 | Wu, xin-tao(wxt@fjirsm.ac.cn) |
| 英文摘要 | A new thioantimonate(iii) with the 2d anionic framework, [3-depnh(2)]sb8s13 center dot h2o 1 (3-depn = 3-dimethylpropanediamine), has been synthesized under solvothermal reactions and characterized by single-crystal x-ray diffraction analysis, ir, elemental analysis, eds, and x-ray powder diffraction. in the 2d porous (sb8s132-)n layer of compound 1, there are two different coordination modes for sb atoms. 1 is a semiconductor with the band gap of e-g = 1.97 ev (629 nm). the thermogravimetric analysis is also discussed. moreover, the impedance spectroscopic measurements of 1 reveal that the bulk conductivity is 5.68 x 10(-6) s cm(-1), and the grain boundary conductivity is 1.43 x 10(-6) s cm(-1). (c) 2009 elsevier b.v. all rights reserved. |
| WOS关键词 | CRYSTAL-STRUCTURES ; SOLVOTHERMAL SYNTHESIS ; THERMAL-STABILITY ; ANTIMONY SULFIDES ; COMPLEXES ; CLUSTERS ; SN |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000273349000023 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2398689 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Xin-Tao |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xin,Sheng, Tian-Lu,Chen, Jian-Shan,et al. Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o[J]. Journal of molecular structure,2009,936(1-3):142-146. |
| APA | Wang, Xin,Sheng, Tian-Lu,Chen, Jian-Shan,Hu, Sheng-Min,Fu, Rui-Biao,&Wu, Xin-Tao.(2009).Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o.Journal of molecular structure,936(1-3),142-146. |
| MLA | Wang, Xin,et al."Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o".Journal of molecular structure 936.1-3(2009):142-146. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。