Organotitanium compound catalysts for transesterification of dimethyl carbonate and phenyl acetate to diphenyl carbonate
文献类型：期刊论文
| 作者 | Cao Ping1,2,3; Yang Jian4; Yang Xiangui1,2; Yao Jie1,2; Wang Yue1,2; Wang Gongying1,2 |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2009 |
| 卷号 | 30期号:1页码:65-68 |
| 关键词 | Titanium oxide acetylacetonate Dimethyl carbonate Phenyl acetate Transesterification Diphenyl carbonate |
| ISSN号 | 0253-9837 |
| 通讯作者 | Cao ping() |
| 英文摘要 | The catalytic performance of sonic organotitanium compounds for transesterification of dimethyl carbonate (i)mc) and phenyl acetate (pa) to diphenyl carbonate (dpc) was measured. it was found that titanium oxide acetylacetonate (tio(acac)(2)) was an efficient catalyst compared with the other compounds. under the optimal conditions (n(pa) = 0.8 mol, n(dmc)/n(pa)= 1/2, n(tio(acac)(2))/n(pa)=0.006, theta = 180 degrees c, i = 4 h), the conversion of dmc was 74.9%, and the selectivity for dpc and mpc was 38.9% and 56.9%, respectively. |
| WOS关键词 | OXIDATIVE CARBONYLATION ; CHEMISTRY ; PHOSGENE ; MG |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000263444300014 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2398753 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao Ping |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Changzhou Inst Chem, Chanzhou Key Lab Green Chem & Technol, Changzhou 213164, Jiangsu, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 4.Yabang Chem Grp Co Ltd, Changzhou 213163, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao Ping,Yang Jian,Yang Xiangui,et al. Organotitanium compound catalysts for transesterification of dimethyl carbonate and phenyl acetate to diphenyl carbonate[J]. Chinese journal of catalysis,2009,30(1):65-68. |
| APA | Cao Ping,Yang Jian,Yang Xiangui,Yao Jie,Wang Yue,&Wang Gongying.(2009).Organotitanium compound catalysts for transesterification of dimethyl carbonate and phenyl acetate to diphenyl carbonate.Chinese journal of catalysis,30(1),65-68. |
| MLA | Cao Ping,et al."Organotitanium compound catalysts for transesterification of dimethyl carbonate and phenyl acetate to diphenyl carbonate".Chinese journal of catalysis 30.1(2009):65-68. |
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来源：中国科学院大学
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