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Chinese Academy of Sciences Institutional Repositories Grid
Room temperature ionic liquids as templates in the synthesis of mesoporous silica via a sol-gel method

文献类型:期刊论文

作者Zhang, Juan1,2; Ma, Yubo1,2; Shi, Feng1; Liu, Lequan1,2; Deng, Youquan1
刊名Microporous and mesoporous materials
出版日期2009-03-01
卷号119期号:1-3页码:97-103
关键词Confined Ionic liquid Mesoporous Silica gel Sol-gel
ISSN号1387-1811
DOI10.1016/j.micromeso.2008.10.003
通讯作者Deng, youquan(ydeng@lzb.ac.cn)
英文摘要With various rtils as templates, amorphous mesoporous silica gel materials were synthesized according to a proper sol-gel method. the materials display pore diameter of 3-12 nm, pore volume of 0.4-1.3 cm(3)/g and bet surface area of 300-800 m(2)/g. the effect of variations of the anions and cations of ils, the alkyl chain length on imidazolium cation and il concentration in the reaction system on the pore structure and thermal stability of the silica gel materials was preliminarily studied. it is suggested that, the pore size of silica gel can be tuned by variations of ils and il content. the different kind of the anions of ills could largely impact the properties of the obtained silica gel materials. the mesoporous silica gels with 1-alkyl-3-methylimidazolium tetrafluoroborate as templates possessed larger pore sizes of 5-12 nm and higher thermal stability than the materials obtained with other ills as templates. (c) 2008 published by elsevier inc.
WOS关键词MOLECULAR-SIEVES ; POROUS SILICA ; SURFACE-AREA ; CATALYSIS ; RECOMMENDATIONS ; COMPOSITE ; WATER ; OXIDE
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000263158700014
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2398785
专题中国科学院大学
通讯作者Deng, Youquan
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Juan,Ma, Yubo,Shi, Feng,et al. Room temperature ionic liquids as templates in the synthesis of mesoporous silica via a sol-gel method[J]. Microporous and mesoporous materials,2009,119(1-3):97-103.
APA Zhang, Juan,Ma, Yubo,Shi, Feng,Liu, Lequan,&Deng, Youquan.(2009).Room temperature ionic liquids as templates in the synthesis of mesoporous silica via a sol-gel method.Microporous and mesoporous materials,119(1-3),97-103.
MLA Zhang, Juan,et al."Room temperature ionic liquids as templates in the synthesis of mesoporous silica via a sol-gel method".Microporous and mesoporous materials 119.1-3(2009):97-103.

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来源:中国科学院大学

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