中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox

文献类型:期刊论文

作者Wang Kun1,2; Du Lin1,2; Ge Maofa1
刊名Journal of environmental sciences-china
出版日期2009
卷号21期号:2页码:137-141
关键词Smog chamber Photochemical reaction Ethyl methyl sulfide Incremental reactivity
ISSN号1001-0742
DOI10.1016/s1001-0742(08)62241-x
通讯作者Ge maofa(gemaofa@iccas.ac.cn)
英文摘要A series of experiments were conducted in a self-made smog chamber at (300 +/- 1) k and 1.01 x 10(5) pa to simulate the photochemical reaction of ethyl methyl sulfide (ems) and nox. the results showed that the higher the initial concentration of ems, the more ozone was generated in the simulative reactions. it was found that the light intensity plays a very important role in the evaluation of ozone formation potential for ems. the parameters of d(o-3-no) and ir (incremental reactivity) were used to quantify the potential of ems on ozone formation. the obtained maximum ir values in this article for the five simulative reactions were 1.55 x 10(-2), 0.99 x 10(-2), 1.36 x 10(-2) 2.47 x 10(-2), and 1.65 x 10(-2), respectively. a comparison between the results we obtained here and the results we obtained previously for di-tert-butyl peroxide and acetylene showed that the potential reactivity of ems on ozone formation was at a relatively low level.
WOS关键词VOLATILE ORGANIC-COMPOUNDS ; INCREMENTAL REACTIVITIES ; MECHANISM ; FLOW
WOS研究方向Environmental Sciences & Ecology
WOS类目Environmental Sciences
语种英语
WOS记录号WOS:000263435800001
出版者SCIENCE PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2399169
专题中国科学院大学
通讯作者Ge Maofa
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
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GB/T 7714
Wang Kun,Du Lin,Ge Maofa. Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox[J]. Journal of environmental sciences-china,2009,21(2):137-141.
APA Wang Kun,Du Lin,&Ge Maofa.(2009).Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox.Journal of environmental sciences-china,21(2),137-141.
MLA Wang Kun,et al."Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox".Journal of environmental sciences-china 21.2(2009):137-141.

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来源:中国科学院大学

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