Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox
文献类型:期刊论文
作者 | Wang Kun1,2; Du Lin1,2; Ge Maofa1 |
刊名 | Journal of environmental sciences-china
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出版日期 | 2009 |
卷号 | 21期号:2页码:137-141 |
关键词 | Smog chamber Photochemical reaction Ethyl methyl sulfide Incremental reactivity |
ISSN号 | 1001-0742 |
DOI | 10.1016/s1001-0742(08)62241-x |
通讯作者 | Ge maofa(gemaofa@iccas.ac.cn) |
英文摘要 | A series of experiments were conducted in a self-made smog chamber at (300 +/- 1) k and 1.01 x 10(5) pa to simulate the photochemical reaction of ethyl methyl sulfide (ems) and nox. the results showed that the higher the initial concentration of ems, the more ozone was generated in the simulative reactions. it was found that the light intensity plays a very important role in the evaluation of ozone formation potential for ems. the parameters of d(o-3-no) and ir (incremental reactivity) were used to quantify the potential of ems on ozone formation. the obtained maximum ir values in this article for the five simulative reactions were 1.55 x 10(-2), 0.99 x 10(-2), 1.36 x 10(-2) 2.47 x 10(-2), and 1.65 x 10(-2), respectively. a comparison between the results we obtained here and the results we obtained previously for di-tert-butyl peroxide and acetylene showed that the potential reactivity of ems on ozone formation was at a relatively low level. |
WOS关键词 | VOLATILE ORGANIC-COMPOUNDS ; INCREMENTAL REACTIVITIES ; MECHANISM ; FLOW |
WOS研究方向 | Environmental Sciences & Ecology |
WOS类目 | Environmental Sciences |
语种 | 英语 |
WOS记录号 | WOS:000263435800001 |
出版者 | SCIENCE PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2399169 |
专题 | 中国科学院大学 |
通讯作者 | Ge Maofa |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Kun,Du Lin,Ge Maofa. Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox[J]. Journal of environmental sciences-china,2009,21(2):137-141. |
APA | Wang Kun,Du Lin,&Ge Maofa.(2009).Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox.Journal of environmental sciences-china,21(2),137-141. |
MLA | Wang Kun,et al."Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and nox".Journal of environmental sciences-china 21.2(2009):137-141. |
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来源:中国科学院大学
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