Novel c-s bond formation through alpha ',beta-elimination of tert-butyl sulfoxonium ylides: a facile approach to chiral sulfoxides
文献类型：期刊论文
| 作者 | Guan, Xiao-Yu1,2,3; Liu, Zhang-Qin1,2; Huang, Hao-Xi1; Yang, Li-Ping3; Jian, Liao1; Hu, Wen-Hao1,3 |
| 刊名 | Synlett
 |
| 出版日期 | 2009-08-13 |
| 期号 | 13页码:2183-2187 |
| 关键词 | Chiral sulfoxides Sulfoxonium ylide Alpha ',beta-elimination |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-0029-1217572 |
| 通讯作者 | Jian, liao(jliao10@cioc.ac.cn) |
| 英文摘要 | Chiral sulfoxides were prepared in excellent enantioselectivity through alpha',beta-elimination of the tert-butyl substituted sulfoxonium ylide intermediates in situ generated from diazoacetates and (r)-n-tert-butylsulfinyl aldimines in the presence of a copper(i) catalyst. |
| WOS关键词 | DIMETHYL SULFOXIDE ; STEREOSELECTIVE-SYNTHESIS ; HYPOCHOLESTEMIC AGENTS ; CARBONYL COMPOUNDS ; INDOLE ALKALOIDS ; DIAZO-COMPOUNDS ; BAKERS-YEAST ; REARRANGEMENT ; SULFONIUM ; OXIDATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000269217900029 |
| 出版者 | GEORG THIEME VERLAG KG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2399391 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Jian, Liao |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guan, Xiao-Yu,Liu, Zhang-Qin,Huang, Hao-Xi,et al. Novel c-s bond formation through alpha ',beta-elimination of tert-butyl sulfoxonium ylides: a facile approach to chiral sulfoxides[J]. Synlett,2009(13):2183-2187. |
| APA | Guan, Xiao-Yu,Liu, Zhang-Qin,Huang, Hao-Xi,Yang, Li-Ping,Jian, Liao,&Hu, Wen-Hao.(2009).Novel c-s bond formation through alpha ',beta-elimination of tert-butyl sulfoxonium ylides: a facile approach to chiral sulfoxides.Synlett(13),2183-2187. |
| MLA | Guan, Xiao-Yu,et al."Novel c-s bond formation through alpha ',beta-elimination of tert-butyl sulfoxonium ylides: a facile approach to chiral sulfoxides".Synlett .13(2009):2183-2187. |
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来源：中国科学院大学
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