Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties
文献类型：期刊论文
| 作者 | Zhao, Jian-Min1,2; Lu, Hai-Yan2; Cao, Jing1,2; Jiang, Yi1,2; Chen, Chuan-Feng1 |
| 刊名 | Tetrahedron letters
 |
| 出版日期 | 2009-01-14 |
| 卷号 | 50期号:2页码:219-222 |
| 关键词 | Triptycene o-quinone Selective synthesis Intramolecular ct interaction Optical and electrochemical properties Dft calculation |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2008.10.128 |
| 通讯作者 | Chen, chuan-feng(cchen@iccas.ac.cn) |
| 英文摘要 | A convenient and efficient method for the selective synthesis of a series of triptycene o-quinone derivatives is described. the triptycene o-quinones, especially the ones containing the methoxy group(s) (electron donor) and the o-quinone group(s) (electron acceptor) simultaneously, show interesting intramolecular ct interactions and electrochemical properties. moreover. dft calculations display that introducing a strong electron-donor group into triptycene o-quinone results in an increasing of the homo energy level, which subsequently decreases the homo-lumo energy gap. (c) 2008 elsevier ltd. all rights reserved. |
| WOS关键词 | CHARGE-TRANSFER INTERACTION ; PARAQUAT DERIVATIVES ; TRANSFER TRANSITION ; FREE-VOLUME ; ROUTE ; COMPLEXATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000263218700021 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2399596 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Chuan-Feng |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Chem Biol, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,et al. Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties[J]. Tetrahedron letters,2009,50(2):219-222. |
| APA | Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,Jiang, Yi,&Chen, Chuan-Feng.(2009).Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties.Tetrahedron letters,50(2),219-222. |
| MLA | Zhao, Jian-Min,et al."Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties".Tetrahedron letters 50.2(2009):219-222. |
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来源：中国科学院大学
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