Nanowire crystals of a rigid rod conjugated polymer
文献类型：期刊论文
| 作者 | Dong, Huanli1,2,3; Jiang, Shidong1,2,3; Jiang, Lang1,2,3; Liu, Yaling4; Li, Hongxiang1,2; Hu, Wenping1,2; Wang, Erjing1,2,3; Yan, Shouke1,2; Wei, Zhongming1,2,3; Xu, Wei1,2 |
| 刊名 | Journal of the american chemical society
 |
| 出版日期 | 2009-12-02 |
| 卷号 | 131期号:47页码:17315-17320 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja907015p |
| 通讯作者 | Hu, wenping(huwp@iccas.ac.cn) |
| 英文摘要 | In this paper, we show that well-defined, highly crystalline nanowires of a rigid rod conjugated polymer, a poly(para-phenylene ethynylene)s derivative with thioacetate end groups (ta-ppe), can be obtained by self-assembling from a dilute solution. structural analyses demonstrate the nanowires with an orthorhombic crystal unit cell wherein the lattice parameters are a approximate to 13.63 angstrom, b approximate to 7.62 angstrom, and c approximate to 5.12 angstrom; in the nanowires the backbones of ta-ppe chains are parallel to the nanowire long axis with their side chains standing on the substrate. the transport properties of the nanowires examined by organic field-effect transistors (ofets) suggest the highest charge carrier mobility approaches 0.1 cm(2)/(v s) with an average value at similar to 10(-2) cm(2)/(v s), which is 3-4 orders higher than that of thin film transistors made by the same polymer, indicating the high performance of the one-dimensional polymer nanowire crystals. these results are particular intriguing and valuable for both examining the intrinsic properties of pipes polymer semiconductors and advancing their potential applications in electronic devices. |
| WOS关键词 | FIELD-EFFECT TRANSISTORS ; SOLID-STATE PHOTOLUMINESCENCE ; CHARGE-TRANSPORT ; THIN-FILMS ; POLARIZED PHOTOLUMINESCENCE ; NONLINEAR OPTICS ; HIGH-PERFORMANCE ; NANOFIBERS ; POLY(2,5-DIALKOXY-P-PHENYLENEETHYNYLENE)S ; POLY(ARYLENEETHYNYLENE)S |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000272207300057 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2400133 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Hu, Wenping |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 3.CAS, Grad Univ, Beijing 100039, Peoples R China 4.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 5.Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA |
| 推荐引用方式 GB/T 7714 | Dong, Huanli,Jiang, Shidong,Jiang, Lang,et al. Nanowire crystals of a rigid rod conjugated polymer[J]. Journal of the american chemical society,2009,131(47):17315-17320. |
| APA | Dong, Huanli.,Jiang, Shidong.,Jiang, Lang.,Liu, Yaling.,Li, Hongxiang.,...&Gong, Xiong.(2009).Nanowire crystals of a rigid rod conjugated polymer.Journal of the american chemical society,131(47),17315-17320. |
| MLA | Dong, Huanli,et al."Nanowire crystals of a rigid rod conjugated polymer".Journal of the american chemical society 131.47(2009):17315-17320. |
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来源：中国科学院大学
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