Catalytic dry oxidation of aniline, benzene, and pyridine adsorbed on a cuo doped activated carbon
文献类型：期刊论文
| 作者 | Li, Bingzheng1,2; Liu, Zhenyu1,3; Lei, Zhiping1,4; Huang, Zhanggen1 |
| 刊名 | Korean journal of chemical engineering
 |
| 出版日期 | 2009-05-01 |
| 卷号 | 26期号:3页码:913-918 |
| 关键词 | Catalytic dry oxidation Cuo doped catalyst Aniline Benzene Pyridine Desorption |
| ISSN号 | 0256-1115 |
| DOI | 10.1007/s11814-009-0153-3 |
| 通讯作者 | Liu, zhenyu(zyliu@sxicc.ac.cn) |
| 英文摘要 | Adsorption of aniline, benzene and pyridine from water on a copper oxide doped activated carbon (cuo/ac) at 30 a degrees c and oxidation behavior of the adsorbed pollutants over cuo/ac in a temperature range up to 500 a degrees c are investigated in tg and tubular-reactor/ms systems. results show that the ac has little activity towards oxidation of the pollutants and cuo is the active oxidation site. oxidation of aniline occurs at 231-349 a degrees c and yields mainly co(2), h(2)o and n(2). oxidation of pyridine occurs at a narrower temperature range, 255-309 a degrees c, after a significant amount of desorption starting at 150 a degrees c. benzene desorbs at temperatures as low as 105 a degrees c and shows no sign of oxidation. the result suggests that adsorption-catalytic dry oxidation is suitable only for the strongly adsorbed pollutants. oxidation temperatures of cuo/ac for organic pollutants are higher than 200 a degrees c and pollutants desorbing easily at temperatures below 200 a degrees c cannot be treated by the method. |
| WOS关键词 | WATER ; ADSORPTION ; POLLUTANTS ; BEHAVIOR ; PHENOL |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000266250000052 |
| 出版者 | SPRINGER |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2400149 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Zhenyu |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 4.Anhui Univ Technol, Sch Chem & Chem, Maanshan 243002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Bingzheng,Liu, Zhenyu,Lei, Zhiping,et al. Catalytic dry oxidation of aniline, benzene, and pyridine adsorbed on a cuo doped activated carbon[J]. Korean journal of chemical engineering,2009,26(3):913-918. |
| APA | Li, Bingzheng,Liu, Zhenyu,Lei, Zhiping,&Huang, Zhanggen.(2009).Catalytic dry oxidation of aniline, benzene, and pyridine adsorbed on a cuo doped activated carbon.Korean journal of chemical engineering,26(3),913-918. |
| MLA | Li, Bingzheng,et al."Catalytic dry oxidation of aniline, benzene, and pyridine adsorbed on a cuo doped activated carbon".Korean journal of chemical engineering 26.3(2009):913-918. |
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来源：中国科学院大学
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