Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands
文献类型：期刊论文
| 作者 | Chi, Shao-Ming1; Wang, Yu-Fei2; Gan, Xin2; Wang, De-Hui2; Fu, Wen-1,2 |
| 刊名 | Central european journal of chemistry
 |
| 出版日期 | 2009-12-01 |
| 卷号 | 7期号:4页码:923-928 |
| 关键词 | Copper(i) complex Phosphine ligand Napaa Crystal structure Photophysical properties |
| ISSN号 | 1895-1066 |
| DOI | 10.2478/s11532-009-0087-y |
| 通讯作者 | Chi, shao-ming() |
| 英文摘要 | A new ligand napaa (napaa = 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine) and its two dinuclear copper(i) complexes, cu(2)(napaa)(dppe)(2)(clo(4))(2) (1) and cu(2)(napaa)(pph(3))(4)(bf(4))(2) (2) (dppe = 1,2-bis(diphenylphosphino)ethane) and pph(3) = triphenylphosphine) were synthesized and characterized, and the structure of 1 was determined by x-ray crystal analysis. each copper atom in 1 has a distorted tetrahedral geometry in which the metal center is associated to napaa and dppe ligands displaying chelating coordination modes and the naphthyridine rings of napaa are almost coplanar. the two complexes exhibit similar electronic absorption spectra with lambda(max) at about 366 nm, which can be tentatively assigned to metal-to-ligand charge-transfer (mlct) transition. the assignment was further supported by density functional theory (dft) calculations. |
| WOS关键词 | CRYSTAL-STRUCTURE ; 1,8-NAPHTHYRIDINE ; CU2+ |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000270541000033 |
| 出版者 | VERSITA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2400324 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chi, Shao-Ming |
| 作者单位 | 1.Chinese Acad Sci, Grad Univ, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650092, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chi, Shao-Ming,Wang, Yu-Fei,Gan, Xin,et al. Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands[J]. Central european journal of chemistry,2009,7(4):923-928. |
| APA | Chi, Shao-Ming,Wang, Yu-Fei,Gan, Xin,Wang, De-Hui,&Fu, Wen-.(2009).Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands.Central european journal of chemistry,7(4),923-928. |
| MLA | Chi, Shao-Ming,et al."Synthesis, structures, and spectroscopic properties of copper(i) complexes bearing 7-acetamido-4-methyl-1,8-naphthyridin-2-carbaldehyde azine and 1,2-bis(diphenylphosphino)ethane ligands".Central european journal of chemistry 7.4(2009):923-928. |
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