1-hexadecyl-3-methylimidazolium ionic liquid as a new cationic surfactant for separation of phenolic compounds by mekc
文献类型:期刊论文
作者 | Niu, Jingang1,2; Qiu, Hongdeng1; Li, Jing1,2; Liu, Xia1; Jiang, Shengxiang1 |
刊名 | Chromatographia
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出版日期 | 2009-05-01 |
卷号 | 69期号:9-10页码:1093-1096 |
关键词 | Micellar electrokinetic capillary chromatography Ionic liquids Cationic surfactant 1-hexadecyl-3-methylimidazolium bromide Phenolic compounds |
ISSN号 | 0009-5893 |
DOI | 10.1365/s10337-009-1028-9 |
通讯作者 | Jiang, shengxiang(sxjiang@1zb.ac.cn) |
英文摘要 | The ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([c(16)mim]br) has been used as a novel cationic surfactant for separation of phenolic compounds, including quinol, phloroglucinol, resorcinol, phenol, p-cresol, and m-nitrophenol, by micellar electrokinetic capillary chromatography (mekc). the effects of buffer concentration and ph, concentration of [c(16)mim]br, and applied potential were studied. use of the optimized buffer (25 mmol l(-1) nah(2)po(4)), 10 mmol l(-1) [c(16)mim]br, and an applied potential of -15 kv enables optimum separation with regard to resolution and migration time. the phenolic compounds were detected at 214 nm. the micelle of this long-alkyl-chain imidazolium ionic liquid acts as a pseudo-stationary phase in this mekc separation. |
WOS关键词 | MICELLAR ELECTROKINETIC CHROMATOGRAPHY ; CAPILLARY CHROMATOGRAPHY ; STATIONARY-PHASE ; AQUEOUS-SOLUTION ; ANION-EXCHANGE ; PERFORMANCE ; ELECTROPHORESIS ; AGGREGATION ; POLYMERS |
WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
WOS类目 | Biochemical Research Methods ; Chemistry, Analytical |
语种 | 英语 |
WOS记录号 | WOS:000266007100043 |
出版者 | VIEWEG |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2400913 |
专题 | 中国科学院大学 |
通讯作者 | Jiang, Shengxiang |
作者单位 | 1.CAS, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Niu, Jingang,Qiu, Hongdeng,Li, Jing,et al. 1-hexadecyl-3-methylimidazolium ionic liquid as a new cationic surfactant for separation of phenolic compounds by mekc[J]. Chromatographia,2009,69(9-10):1093-1096. |
APA | Niu, Jingang,Qiu, Hongdeng,Li, Jing,Liu, Xia,&Jiang, Shengxiang.(2009).1-hexadecyl-3-methylimidazolium ionic liquid as a new cationic surfactant for separation of phenolic compounds by mekc.Chromatographia,69(9-10),1093-1096. |
MLA | Niu, Jingang,et al."1-hexadecyl-3-methylimidazolium ionic liquid as a new cationic surfactant for separation of phenolic compounds by mekc".Chromatographia 69.9-10(2009):1093-1096. |
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来源:中国科学院大学
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