Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)
文献类型:期刊论文
作者 | Dang, Zhen-Hua1,2; Mou, Si1; Xu, Li1 |
刊名 | Journal of solid state chemistry |
出版日期 | 2009-10-01 |
卷号 | 182期号:10页码:2840-2845 |
ISSN号 | 0022-4596 |
关键词 | Molybdenum Lanthanide Heterometallic cluster Hydrogen bond Crystal structure Supramolecular |
DOI | 10.1016/j.jssc.2009.07.051 |
通讯作者 | Xu, li(xli@fjirsm.ac.cn) |
英文摘要 | The reactions of lncl(3)center dot 6h(2)o (ln = eu or dy) and na-2[mo2o3s(hnta)(2)]center dot 6h(2)o afford na[mo2o3s(hnta)(2)](2)center dot eu(h2o)(9)center dot 3h(2)o (1) (nta = nitrilotriacetate) and na{(h2o)(6)dy[mo2o3s(hnta)(2)](2)}center dot 7.5h(2)o (2), respectively. the [mo2o3s(hnta)(2)](2-) cluster units of 1 are interconnected by na+ into a 3-d open framework with rutile topology templated by eu(h2o)(9)(3+). the coordination of [mo2o3s(hnta)(2)](2-) to the slightly smaller dy3+ ion of greater ionic potential as a consequence of lanthanide contraction has been observed to form the pentanuclear heterometallic {dy(h2o)(6)[mo2o3s(hnta)(2)](2)}(-), which is linked by na+ and hydrogen bonds between the protonated carboxylate groups into a 3-d supramolecular framework. the weak antiferromagnetic interactions between the dy3+ ions of 2 have been observed. (c) 2009 elsevier inc. all rights reserved. |
WOS关键词 | MOLYBDENUM(V) ; COMPLEXES ; CRYSTAL ; RUTILE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
语种 | 英语 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
WOS记录号 | WOS:000270747800037 |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2401318 |
专题 | 中国科学院大学 |
通讯作者 | Xu, Li |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Dang, Zhen-Hua,Mou, Si,Xu, Li. Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)[J]. Journal of solid state chemistry,2009,182(10):2840-2845. |
APA | Dang, Zhen-Hua,Mou, Si,&Xu, Li.(2009).Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy).Journal of solid state chemistry,182(10),2840-2845. |
MLA | Dang, Zhen-Hua,et al."Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)".Journal of solid state chemistry 182.10(2009):2840-2845. |
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来源:中国科学院大学
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